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- W1972051284 abstract "The crystal structure of monoclinic CuTeO3 (CuTeO3-II) was determined by direct methods and Fourier summations from single-crystal X-ray data (a = 5.214(1) Å, b = 9.108(2) Å, c = 5.965(1) Å, β = 95.06(1)°; space group P21n - C52h; Z = 4; R = 0.035). The Cu atom is [4 + 1] coordinated and the Te atom [3 + 2] coordinated to oxygen atoms. Each two CuO4 “square” is combined via a common OO edge to formal Cu2O6 groups, which are moreover combined by the fifth CuO bond to formal CuO3 sheets parallel to (010). The connection of the coordination polyhedra around the Cu and Te atoms results in a framework. CuTeO3-II was synthesized under hydrothermal conditions at 500(5) K. A comparison with CuTeO3-I (orthorhombic) based on crystal chemistry is given." @default.
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- W1972051284 date "1987-12-01" @default.
- W1972051284 modified "2023-10-18" @default.
- W1972051284 title "Dimorphism of hydrothermal synthesized copper tellurite, CuTeO3: The structure of a monoclinic representative" @default.
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- W1972051284 doi "https://doi.org/10.1016/0022-4596(87)90236-2" @default.
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