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- W1972066802 abstract "Abstract New complexes of the general formulae MnX 2 L 2 (X = Cl,Br), MnBr 2 L 3 , CoX 2 L 2 (X = Cl, Br, I, NCS, NO 3 ), NiX 2 L 2 (X = Cl, NO 3 ), NiBr 2 L 3 ·H 2 O, NiL 2 L 4 ·H 2 O, CuCl 2 L, CuBr 2 L 2 ·H 2 O, Cu(NO 3 ) 2 L 2 , ZnX 2 L 2 (X = Cl, Br, NO 3 , Zn(NCS) 2 L 2 ·H 2 O, CdX 2 L 2 (X = I, NO 3 ) and HgCl 2 L, where L is 1-methyl-3,4-diphenylpyrazole, have been prepared and characterized by elemental analysis, conductivity measurements, magnetic moments and spectral ( 1 H-NMR, IR and electronic) studies. The ligands is formed by the reaction between benzil and N,N-dimethylhydrazine. The nitrogen of the >CN bond is the donor atom to the metal ions. The bis-ligand halide complexes are pseudotetrahedral, while the nitrate complexes contain octahedrally coordinated metal ions. The IR spectra of MCl 2 L (M = Cu, Hg) are indicative of the presence of both terminal and bridging metal-halogen bonds supporting polymeric structures. The stereochemistry and the nature of the nickel(II) complexes are markedly dependent upon the anions; the chloride complex is pseudotetrahedral, the iodide square planar, the nitrate polymeric octahedral, while the proposed structural formula for NiBr 2 L 3 ·H 2 O comprises Nickel(II) atoms present in both square planar and octahedral coordination environments." @default.
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- W1972066802 date "1985-08-01" @default.
- W1972066802 modified "2023-09-26" @default.
- W1972066802 title "Metal complexes of 1-methyl-3,4-diphenylpyrazole, a ligand formed by the reaction between benzil and N,N,-dimethylhydrazine" @default.
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- W1972066802 doi "https://doi.org/10.1016/s0020-1693(00)89075-1" @default.
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