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- W1972081940 abstract "Luminescent materials have been prepared by wet impregnation of Europium (III) dibenzoylmethane complexes in either non-silylated or silylated mesoporous MCM-48 silica. Silylation and incorporation of the Eu (III) complex were confirmed by Nuclear Magnetic Resonance, N2-sorption, X-ray diffraction and Infrared spectroscopy. The luminescence properties were investigated at room and high temperatures up to 200 °C. Information on host–guest interactions were collected by analyzing the optical characteristics of the Eu (III) ions in the different media. In particular, the intensity parameter Ω2 is confirmed to be a useful spectroscopic probe for Eu (III) first coordination shell interaction. The role of the O2−—Eu3+ charge transfer band and the impact of the silylation on the luminescence properties at room and high temperatures is demonstrated." @default.
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- W1972081940 date "2007-05-01" @default.
- W1972081940 modified "2023-09-26" @default.
- W1972081940 title "Luminescence properties of Eu3+ β-diketonates incorporated in cubic mesoporous silica" @default.
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- W1972081940 doi "https://doi.org/10.1016/j.jlumin.2006.01.356" @default.
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