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- W1972090659 abstract "Ba1−xBixTi1−xYbx/2Fex/2O3 ceramics were fabricated by the solid state reaction method. X-ray diffraction analyses show 0 ≤ x ≤ 0.04 ceramics to have an average crystal structure described by the non-centrosymmetric tetragonal P4 mm space group, whereas x ≥ 0.08 ceramics are consistent with a centrosymmetric cubic perovskite (space group Pm-3 m). Coexistence of both tetragonal and cubic symmetries is observed for x = 0.06. Raman spectroscopy analysis corroborate a change in average structure with increasing x, but also show the local crystal symmetry for x ≥ 0.08 ceramics to deviate from the idealized cubic perovskite structure. Dielectric data show a ferroelectric-to-relaxor crossover, which occurs in conjunction with the change in both the average and local crystal symmetry as indicated by X-ray and Raman data. For x ≥ 0.08, ceramics exhibit relaxor behavior, which is also accompanied by a shift of the permittivity maxima towards higher temperatures with increasing x." @default.
- W1972090659 created "2016-06-24" @default.
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- W1972090659 date "2013-08-01" @default.
- W1972090659 modified "2023-10-02" @default.
- W1972090659 title "Structure–property relationships in BaTiO3–BiFeO3–BiYbO3 ceramics" @default.
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- W1972090659 doi "https://doi.org/10.1016/j.jeurceramsoc.2013.01.011" @default.
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