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- W1972141731 abstract "Twenty-two dichlorinated methylketones have been submitted to Favorskii rearrangement in NaOMeMeOH. Distribution of products is strongly dependent on substitution. Primary dichloromethyl-ketones (R2 = H) gave rise to Favorskii esters only. Results are explained by a cyclopropanone intermediate, which is formed stereospecifically by disrotative closure of a delocalized zwitter-ion. Opening of the cyclopropanone intermediate is affected by steric and electronic influences. On the contrary secondary dichloromethylketones (R2 ≠ H) afforded Favorskii esters next to methoxyketones derived from a solvolysis mechanism." @default.
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- W1972141731 date "1975-01-01" @default.
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- W1972141731 title "The favorskii rearrangement of dichlorinated methylketones" @default.
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- W1972141731 doi "https://doi.org/10.1016/0040-4020(75)80198-0" @default.
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