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- W1972161117 abstract "Abstract In the present work, the cracking and isomerization of methylcyclohexane on a partially exchanged NaHY zeolite has been studied in the presence of H 2 and N 2 , at atmospheric pressure and 350, 400 and 450 °C. Hydrogen has a negative influence on the reaction rates for the two reactions, while activation energies remain unaffected. A possible mechanism for the interaction of H 2 with carbocations has been studied by molecular orbital calculations, and it has been found that H 2 can inhibit these reactions by formation of a complex [carbocation-H 2 ]." @default.
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- W1972161117 date "1983-04-01" @default.
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- W1972161117 title "A study on the deactivation of carbocations by molecular hydrogen" @default.
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- W1972161117 doi "https://doi.org/10.1016/0304-5102(83)80015-7" @default.
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