FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W1972192807> ?p ?o ?g. }

• W1972192807 endingPage "2791" @default.
• W1972192807 startingPage "2780" @default.
• W1972192807 abstract "Vibrational energy transfer has been monitored from the 61 level of 1B2u(S1) benzene seeded in rare gas supersonic free jet expansions at X/D=5, where the temperature is calculated to be ∼10 K. The monatomic collision partners helium, neon, argon, and krypton form the subject of this study. Consequently, transfer is limited to one mechanism, transfer of vibrational energy in benzene to translational energy of the collision pair. The vibrational energy transfer is followed using time resolved, dispersed fluorescence spectroscopy. While there are five possible destination levels, only three are found to be important. These are transfer to the 162 level and transfer to the spectrally unresolved 111 and 161 levels. Negligible transfer is observed to both of the remaining two accessible levels, 00 and 41. It is found that the branching ratio for the two destination channels is insensitive to the identity of the collision partner. The branching ratios are reproduced by calculations based on SSH-T theory. The calculations suggest that the insensitivity of the branching ratio to the collision partner is fortuitous: while the combined 111/161 channel retains approximately the same ratio to 162 for all collision partners, the relative importance of the 111 and 161 levels themselves is collision partner dependent. Evidence is presented suggesting that there is significant rotational excitation accompanying the vibrational energy transfer in the case of heavy collision partners. This study, by establishing the behavior of vibration to translation transfer, forms the basis for further studies of the role of vibration to rotation and, subsequently, vibration to vibration mechanisms in vibrational energy transfer in benzene at low temperatures." @default.
• W1972192807 created "2016-06-24" @default.
• W1972192807 creator A5032863874 @default.
• W1972192807 creator A5033548127 @default.
• W1972192807 date "1995-02-15" @default.
• W1972192807 modified "2023-09-26" @default.
• W1972192807 title "Vibrational energy transfer from the 6¹ level of <i>S</i>₁ (¹<i>B</i>_2<i>u</i>) benzene in a supersonic expansion. I. Monatomic collision partners" @default.
• W1972192807 cites W1963506441 @default.
• W1972192807 cites W1965730885 @default.
• W1972192807 cites W1970955384 @default.
• W1972192807 cites W1972687462 @default.
• W1972192807 cites W1978852841 @default.
• W1972192807 cites W1979135228 @default.
• W1972192807 cites W1979569624 @default.
• W1972192807 cites W1981308627 @default.
• W1972192807 cites W1982372886 @default.
• W1972192807 cites W1983131870 @default.
• W1972192807 cites W1996172316 @default.
• W1972192807 cites W1998686796 @default.
• W1972192807 cites W2010368947 @default.
• W1972192807 cites W2016406830 @default.
• W1972192807 cites W2018153956 @default.
• W1972192807 cites W2019253259 @default.
• W1972192807 cites W2020461127 @default.
• W1972192807 cites W2028922198 @default.
• W1972192807 cites W2033664697 @default.
• W1972192807 cites W2037022641 @default.
• W1972192807 cites W2037938941 @default.
• W1972192807 cites W2042994552 @default.
• W1972192807 cites W2044939118 @default.
• W1972192807 cites W2045164360 @default.
• W1972192807 cites W2058184367 @default.
• W1972192807 cites W2067937124 @default.
• W1972192807 cites W2073719842 @default.
• W1972192807 cites W2083861844 @default.
• W1972192807 cites W2083980163 @default.
• W1972192807 cites W2084550876 @default.
• W1972192807 cites W2088271622 @default.
• W1972192807 cites W2091334754 @default.
• W1972192807 cites W2094449488 @default.
• W1972192807 cites W2144156709 @default.
• W1972192807 cites W2951700279 @default.
• W1972192807 cites W4246034615 @default.
• W1972192807 doi "https://doi.org/10.1063/1.468654" @default.
• W1972192807 hasPublicationYear "1995" @default.
• W1972192807 type Work @default.
• W1972192807 sameAs 1972192807 @default.
• W1972192807 citedByCount "16" @default.
• W1972192807 crossrefType "journal-article" @default.
• W1972192807 hasAuthorship W1972192807A5032863874 @default.
• W1972192807 hasAuthorship W1972192807A5033548127 @default.
• W1972192807 hasConcept C106447425 @default.
• W1972192807 hasConcept C121332964 @default.
• W1972192807 hasConcept C121704057 @default.
• W1972192807 hasConcept C184779094 @default.
• W1972192807 hasConcept C185592680 @default.
• W1972192807 hasConcept C38652104 @default.
• W1972192807 hasConcept C41008148 @default.
• W1972192807 hasConcept C46460574 @default.
• W1972192807 hasConcept C521692839 @default.
• W1972192807 hasConcept C522602180 @default.
• W1972192807 hasConcept C546029482 @default.
• W1972192807 hasConcept C547737533 @default.
• W1972192807 hasConcept C62520636 @default.
• W1972192807 hasConcept C83581075 @default.
• W1972192807 hasConceptScore W1972192807C106447425 @default.
• W1972192807 hasConceptScore W1972192807C121332964 @default.
• W1972192807 hasConceptScore W1972192807C121704057 @default.
• W1972192807 hasConceptScore W1972192807C184779094 @default.
• W1972192807 hasConceptScore W1972192807C185592680 @default.
• W1972192807 hasConceptScore W1972192807C38652104 @default.
• W1972192807 hasConceptScore W1972192807C41008148 @default.
• W1972192807 hasConceptScore W1972192807C46460574 @default.
• W1972192807 hasConceptScore W1972192807C521692839 @default.
• W1972192807 hasConceptScore W1972192807C522602180 @default.
• W1972192807 hasConceptScore W1972192807C546029482 @default.
• W1972192807 hasConceptScore W1972192807C547737533 @default.
• W1972192807 hasConceptScore W1972192807C62520636 @default.
• W1972192807 hasConceptScore W1972192807C83581075 @default.
• W1972192807 hasIssue "7" @default.
• W1972192807 hasLocation W19721928071 @default.
• W1972192807 hasOpenAccess W1972192807 @default.
• W1972192807 hasPrimaryLocation W19721928071 @default.
• W1972192807 hasRelatedWork W1964663526 @default.
• W1972192807 hasRelatedWork W1966799389 @default.
• W1972192807 hasRelatedWork W1995421311 @default.
• W1972192807 hasRelatedWork W2001210027 @default.
• W1972192807 hasRelatedWork W2006008138 @default.
• W1972192807 hasRelatedWork W2022449637 @default.
• W1972192807 hasRelatedWork W2057809746 @default.
• W1972192807 hasRelatedWork W2091418955 @default.
• W1972192807 hasRelatedWork W2103840285 @default.
• W1972192807 hasRelatedWork W2165186758 @default.
• W1972192807 hasVolume "102" @default.
• W1972192807 isParatext "false" @default.
• W1972192807 isRetracted "false" @default.
• W1972192807 magId "1972192807" @default.
• W1972192807 workType "article" @default.