FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W1972251528> ?p ?o ?g. }

• W1972251528 endingPage "18" @default.
• W1972251528 startingPage "1" @default.
• W1972251528 abstract "New findings on calcium oxalate monohydrate, monoclinic lysozyme and potassium dihydrophosphate crystal growth are presented and discussed. Atomic force microscopy was applied to measure step rates on CaOx and monoclinic lysozyme faces to understand kink kinetics. High precision Michaelson interferometry allowed to discover step splitting on the (1 0 1) KH2PO4 face growing from turbulent solution. In all three cases, aqueous solutions at room temperature were used. CaOx was grown from solution in which the ion concentration ratio ξ≡[Ox]/[Ca]=5×10-2, 10−1, 1, 10, 20. The rate v of steps one lattice spacing high on the (1 0 0) face reach maximum at ξ=1. Attachment and detachment statistics of two types of particles (Ca and Ox) to a kink on the step of a non-Kossel crystal predicted the reciprocal kink propagation rate to be 1/v ∼ ξ1/2+ξ−1/2, consistent with experiment. Step morphology on the (1 0 1) face of monoclinic lysozyme suggests rhombic, about rectangular 2D critical nucleus. In such a nucleus, two mutually parallel, though crystallographically different steps making the opposite edges, are supposed to be equal. The segment lengths pinned at dislocation outcrop are found to be very different and experience huge scattering. These phenomena, treated as a result of different kink nucleation rates on parallel nearly kink-free steps “looking” to the opposite directions, are of kinetic rather than of thermodynamic origin. Contrary to conventional observations, in a turbulent solution flow the average step bunch width and height were found to reach limits as bunches propagate along the face. These limits decrease when the flow rate increases from ∼60 to 200 cm/s. The phenomenon is explained by the turbulent nature of the solution flow. In this flow, due to penetration of turbulent eddies, diffusivity within the viscous solution boundary layer, D=D0+0.5 uτ y, quickly increases with the distance y from the interface since the friction velocity, uτ, reaches several cm/s. Therefore, molecular diffusivity, D0 ≅ 10−5 cm2/s, is significant only within the ∼20–40 nm thick solution layer over the interface. As the flow rate increases, the turbulent mixed solution approaches the growing stepped crystal face closer and shrinks the range within which steps interact with one another through their diffusion fields. This weak interaction results in step splitting." @default.
• W1972251528 created "2016-06-24" @default.
• W1972251528 creator A5071575987 @default.
• W1972251528 creator A5071957209 @default.
• W1972251528 creator A5087449907 @default.
• W1972251528 date "2005-02-01" @default.
• W1972251528 modified "2023-10-14" @default.
• W1972251528 title "Steps in solution growth: dynamics of kinks, bunching and turbulence" @default.
• W1972251528 cites W1487100945 @default.
• W1972251528 cites W1599175522 @default.
• W1972251528 cites W1642958179 @default.
• W1972251528 cites W1965571863 @default.
• W1972251528 cites W1985396160 @default.
• W1972251528 cites W1986153175 @default.
• W1972251528 cites W1987253937 @default.
• W1972251528 cites W1987398820 @default.
• W1972251528 cites W2002929671 @default.
• W1972251528 cites W2010352499 @default.
• W1972251528 cites W2011732764 @default.
• W1972251528 cites W2012630830 @default.
• W1972251528 cites W2022982817 @default.
• W1972251528 cites W2025739397 @default.
• W1972251528 cites W2029376783 @default.
• W1972251528 cites W2032010952 @default.
• W1972251528 cites W2036535239 @default.
• W1972251528 cites W2041287953 @default.
• W1972251528 cites W2044349314 @default.
• W1972251528 cites W2056951929 @default.
• W1972251528 cites W2058467248 @default.
• W1972251528 cites W2059296615 @default.
• W1972251528 cites W2067882340 @default.
• W1972251528 cites W2071305297 @default.
• W1972251528 cites W2073156415 @default.
• W1972251528 cites W2082068401 @default.
• W1972251528 cites W2084767228 @default.
• W1972251528 cites W2085023811 @default.
• W1972251528 cites W2091114377 @default.
• W1972251528 cites W2093165968 @default.
• W1972251528 cites W2094255504 @default.
• W1972251528 cites W2126559242 @default.
• W1972251528 cites W2485560134 @default.
• W1972251528 cites W4254670015 @default.
• W1972251528 cites W4255944549 @default.
• W1972251528 cites W44846989 @default.
• W1972251528 doi "https://doi.org/10.1016/j.jcrysgro.2004.10.094" @default.
• W1972251528 hasPublicationYear "2005" @default.
• W1972251528 type Work @default.
• W1972251528 sameAs 1972251528 @default.
• W1972251528 citedByCount "50" @default.
• W1972251528 countsByYear W19722515282013 @default.
• W1972251528 countsByYear W19722515282014 @default.
• W1972251528 countsByYear W19722515282015 @default.
• W1972251528 countsByYear W19722515282016 @default.
• W1972251528 countsByYear W19722515282017 @default.
• W1972251528 countsByYear W19722515282018 @default.
• W1972251528 countsByYear W19722515282019 @default.
• W1972251528 countsByYear W19722515282020 @default.
• W1972251528 countsByYear W19722515282022 @default.
• W1972251528 countsByYear W19722515282023 @default.
• W1972251528 crossrefType "journal-article" @default.
• W1972251528 hasAuthorship W1972251528A5071575987 @default.
• W1972251528 hasAuthorship W1972251528A5071957209 @default.
• W1972251528 hasAuthorship W1972251528A5087449907 @default.
• W1972251528 hasConcept C115624301 @default.
• W1972251528 hasConcept C120665830 @default.
• W1972251528 hasConcept C121332964 @default.
• W1972251528 hasConcept C147789679 @default.
• W1972251528 hasConcept C184651966 @default.
• W1972251528 hasConcept C185592680 @default.
• W1972251528 hasConcept C191486275 @default.
• W1972251528 hasConcept C199360897 @default.
• W1972251528 hasConcept C200447597 @default.
• W1972251528 hasConcept C26456737 @default.
• W1972251528 hasConcept C2781285689 @default.
• W1972251528 hasConcept C41008148 @default.
• W1972251528 hasConcept C61048295 @default.
• W1972251528 hasConcept C61276311 @default.
• W1972251528 hasConcept C8010536 @default.
• W1972251528 hasConcept C97355855 @default.
• W1972251528 hasConceptScore W1972251528C115624301 @default.
• W1972251528 hasConceptScore W1972251528C120665830 @default.
• W1972251528 hasConceptScore W1972251528C121332964 @default.
• W1972251528 hasConceptScore W1972251528C147789679 @default.
• W1972251528 hasConceptScore W1972251528C184651966 @default.
• W1972251528 hasConceptScore W1972251528C185592680 @default.
• W1972251528 hasConceptScore W1972251528C191486275 @default.
• W1972251528 hasConceptScore W1972251528C199360897 @default.
• W1972251528 hasConceptScore W1972251528C200447597 @default.
• W1972251528 hasConceptScore W1972251528C26456737 @default.
• W1972251528 hasConceptScore W1972251528C2781285689 @default.
• W1972251528 hasConceptScore W1972251528C41008148 @default.
• W1972251528 hasConceptScore W1972251528C61048295 @default.
• W1972251528 hasConceptScore W1972251528C61276311 @default.
• W1972251528 hasConceptScore W1972251528C8010536 @default.
• W1972251528 hasConceptScore W1972251528C97355855 @default.
• W1972251528 hasIssue "1-2" @default.
• W1972251528 hasLocation W19722515281 @default.
• W1972251528 hasOpenAccess W1972251528 @default.

• next