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• W1972289018 abstract "The title compound 1b ideally meets the theoretical requirements for the occurrence of an adiabatic photoisomerization in the lowest excited state (11b*) and, indeed, the predominant primary photoreaction observed is the conversion to its fluorescent valence isomer 10b, 10c-methano-cis-10b 10c-dihydropyrene (11a*). The mechanism for the formation often previously observed photoproduct 8b, 9a-dihydro-9H - cyclopropa[e]pyrene (4a) has been analyzed in some detail (Scheme). Below − 30°C the reaction path consists of a three quantum process (two di-π-methane rearrangements and photochemical 1,7-H shift) involving two thermally stable, but light-sensitive isomers 8,11b-methanocyclodeca[cde]naphthalene (2b) and 9H -cyclohepta[def]-phenanthrene (3b). At room temperature the rearrangement 2b→4a proceeds with a single excitation step bypassing the ground state intermediate 3b. Finally, upon prolonged irradiation of (4a), the methylene group is lost to yield pyrene. Compound 2b completes the series of all possible adducts of methylene to a CC bond of pyrene." @default.
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• W1972289018 date "1984-02-01" @default.
• W1972289018 modified "2023-09-26" @default.
• W1972289018 title "Photoisomerization pathways of 8,16-methno[2.2]metacyclopane-1,9-diene. A model case for adiabatic electrocyclic ring closure in the excited singlet state" @default.
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• W1972289018 doi "https://doi.org/10.1002/hlca.19840670137" @default.
• W1972289018 hasPublicationYear "1984" @default.
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