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- W1972355963 endingPage "953" @default.
- W1972355963 startingPage "953" @default.
- W1972355963 abstract "The reaction of [Pd(CH3CN)2Cl2] with N′-substituted N,N-di(2-picolyl)amine-based ancillary ligands, for example N,N-di(2-picolyl)cyclohexylmethylamine (L1), N,N-di(2-picolyl)benzylamine (L2), N,N-di(2-picolyl)aniline (L3), and 1,4-bis[bis(2-pyridylmethyl)aminomethyl]benzene (L4), in the presence of NaClO4 in ethanol yields a new series of [(NN′N)PdCl]X (X = ClO4, Cl) complexes, i.e. mononuclear [LnPdCl]ClO4 (Ln = L1, L2, L3) and binuclear [L4Pd2Cl2]Cl2. X-Ray crystallographic analysis determined that the Pd atom in complexes [(NN′N)PdCl]X showed a slightly distorted square-planar geometry involving three nitrogen atoms and a chlorido ligand. Moreover, the unit cell included a ClO4– or Cl– anion as the counterion. The complex [L1PdCl]ClO4 showed the highest catalytic activity for the polymerisation of methyl methacrylate in the presence of modified methylaluminoxane at 60°C among the mononuclear PdII complexes. Specifically, the activity of binuclear [L4Pd2Cl2]Cl2 was 2-fold higher than the corresponding mononuclear [L2PdCl]ClO4 per active palladium metal centre." @default.
- W1972355963 created "2016-06-24" @default.
- W1972355963 creator A5003465369 @default.
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- W1972355963 creator A5069167592 @default.
- W1972355963 creator A5072254554 @default.
- W1972355963 creator A5075619909 @default.
- W1972355963 date "2014-01-01" @default.
- W1972355963 modified "2023-09-23" @default.
- W1972355963 title "Synthesis and Structural Characterisation of Palladium(II) Complexes with N,N′,N-Tridentate N′-Substituted N,N-Di(2-picolyl)amines and their Application to Methyl Methacrylate Polymerisation" @default.
- W1972355963 cites W1967298519 @default.
- W1972355963 cites W1970433277 @default.
- W1972355963 cites W1972684821 @default.
- W1972355963 cites W1973195722 @default.
- W1972355963 cites W1976718341 @default.
- W1972355963 cites W1977767796 @default.
- W1972355963 cites W1978212017 @default.
- W1972355963 cites W1981740692 @default.
- W1972355963 cites W1985735719 @default.
- W1972355963 cites W1986430124 @default.
- W1972355963 cites W1987857014 @default.
- W1972355963 cites W1988774858 @default.
- W1972355963 cites W1990762263 @default.
- W1972355963 cites W1992189547 @default.
- W1972355963 cites W1998332060 @default.
- W1972355963 cites W1998810293 @default.
- W1972355963 cites W2003016175 @default.
- W1972355963 cites W2004004549 @default.
- W1972355963 cites W2006963632 @default.
- W1972355963 cites W2007783666 @default.
- W1972355963 cites W2011126904 @default.
- W1972355963 cites W2012796644 @default.
- W1972355963 cites W2013240048 @default.
- W1972355963 cites W2016099098 @default.
- W1972355963 cites W2025610802 @default.
- W1972355963 cites W2026481878 @default.
- W1972355963 cites W2031543338 @default.
- W1972355963 cites W2032524371 @default.
- W1972355963 cites W2032592116 @default.
- W1972355963 cites W2034312013 @default.
- W1972355963 cites W2038072320 @default.
- W1972355963 cites W2040172223 @default.
- W1972355963 cites W2040254257 @default.
- W1972355963 cites W2041234176 @default.
- W1972355963 cites W2041435631 @default.
- W1972355963 cites W2042035052 @default.
- W1972355963 cites W2042729782 @default.
- W1972355963 cites W2045599775 @default.
- W1972355963 cites W2047762078 @default.
- W1972355963 cites W2049969384 @default.
- W1972355963 cites W2052724054 @default.
- W1972355963 cites W2053449162 @default.
- W1972355963 cites W2054854542 @default.
- W1972355963 cites W2055637806 @default.
- W1972355963 cites W2056342693 @default.
- W1972355963 cites W2056409506 @default.
- W1972355963 cites W2056791019 @default.
- W1972355963 cites W2060707520 @default.
- W1972355963 cites W2063357786 @default.
- W1972355963 cites W2064436453 @default.
- W1972355963 cites W2066659345 @default.
- W1972355963 cites W2066971170 @default.
- W1972355963 cites W2068979471 @default.
- W1972355963 cites W2070257346 @default.
- W1972355963 cites W2074161757 @default.
- W1972355963 cites W2077039002 @default.
- W1972355963 cites W2077287061 @default.
- W1972355963 cites W2078923136 @default.
- W1972355963 cites W2079693928 @default.
- W1972355963 cites W2080438733 @default.
- W1972355963 cites W2082630786 @default.
- W1972355963 cites W2082637041 @default.
- W1972355963 cites W2083361606 @default.
- W1972355963 cites W2085480684 @default.
- W1972355963 cites W2089240109 @default.
- W1972355963 cites W2089495471 @default.
- W1972355963 cites W2091946629 @default.
- W1972355963 cites W2091973876 @default.
- W1972355963 cites W2093351823 @default.
- W1972355963 cites W2101719270 @default.
- W1972355963 cites W2110967280 @default.
- W1972355963 cites W2122035956 @default.
- W1972355963 cites W2124141517 @default.
- W1972355963 cites W2132654860 @default.
- W1972355963 cites W2152983489 @default.
- W1972355963 cites W2153002966 @default.
- W1972355963 cites W2156536941 @default.
- W1972355963 cites W2156920774 @default.
- W1972355963 cites W2160744965 @default.
- W1972355963 doi "https://doi.org/10.1071/ch13731" @default.
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