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- W1972372368 abstract "Cs2BeCl4 kristallisiert im β-K2SO4-Typ (orthorhombisch, Pnma, Z = 4, a = 964,2(4), b = 717,8(3), c = 1246,8(5) pm), Cs2YbCl4 im K2NiF4-Typ (tetragonal, I4/mmm, Z = 2, a = 541,8(2), c = 1727,6(10) pm). Sie sind die Endglieder minimalen bzw. maximalen molaren Volumens (Ausnahme: Cs2TmCl4) der homologen Reihe Cs2MCl4. Die Anwendung des „Theorems der bevorzugten Volumina”︁ legt nahe, daß auch die übrigen Mitglieder der Reihe Cs2MCl4 nur einem dieser beiden Strukturtypen (β-K2SO4- bzw. K2NiF4-Typ) angehören können. Cs2BeCl4 and Cs2YbCl4: End Members of the Homologous Series Cs2MCl4 Cs2BeCl4 belongs to the β-K2SO4 type structure (orthorhombic, Pnma, Z = 4, a = 964.2(4), b = 717.8(3), c = 1246.8(5) pm) and Cs2YbCl4 to the K2NiF4 type (tetragonal, I4/mmm, Z = 2, a = 541.8(2), c = 1727.6(10) pm). They are with the exception of Cs2TmCl4 the end members of minimum and maximum molar volume of the homologous series Cs2MCl4. The application of the “theorem of optimal (preferred) volumes” suggests that the other members of the series also can only belong to one of these two structure types (β-K2SO4 and K2NiF4 type, respectively)." @default.
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- W1972372368 date "1984-08-01" @default.
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- W1972372368 title "Cs2BeCl4 und Cs2 YbCl4: Endglieder der homologen Reihe Cs2MCl4" @default.
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- W1972372368 doi "https://doi.org/10.1002/zaac.19845150815" @default.
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