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- W1972372649 abstract "The stoichiometry ranges of Cu2O1 + γ, CuO1 + γ, Cu0.984Fe2.016O4 + γ, Cu1.011Fe1.989O4 + γ, and Cu0.551Fe2.449O4 + γ were established by high temperature electrochemical measurements in a stabilized zirconia electrolyte cell. The results were consistent with neutral oxygen vacancies for oxygen deficit and neutral cation vacancies for oxygen excess in cuprite, neutral oxygen vacancies in Cu1.011Fe1.989O4 + γ and Cu0.551Fe2.449O4 + γ, neutral cation vacancies in Cu0.984Fe2.016O4 + γ and neutral associations of interstitial copper atoms in cupric oxide. The defect structures of these compounds were derived from the consideration of equilibrium with respect to oxygen between the solid and the gas phase. The absolute magnitudes of nonstoichiometry, defect concentrations and the enthalpy of defect formation were calculated. The enthalpies of the formation of Schottky defects in “Cu2O” and “CuFe2O4” were calculated." @default.
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- W1972372649 date "1972-09-01" @default.
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- W1972372649 title "Nonstoichiometry and defect structures in copper oxides and ferrites" @default.
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- W1972372649 doi "https://doi.org/10.1016/0022-4596(72)90024-2" @default.
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