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- W1972455054 abstract "Abstract A novel vic-dioxime S,S′-bis[2-(4′-benzylidenamino-benzo-15-crown-5)dithioglyoxime (6), with crown ether groups has been synthesized from the reaction of 4′-formylbenzo(15-crown-5) and S,S′-bis(2-aminophenyl)dithioglyoxime (4), which has been synthesized from the potassium salt of 2-aminothiophenol and dichloroglyoxime. Mononuclear complexes with a metal:ligand ratio of 1:2 have been isolated for nickel(II) and cobalt(III). The reaction of mononuclear complexes with copper(I) and cadmium(II) gives heterotrinuclear complexes. The structure of dioximes and their complexes are proposed according to elemental analyses, 1H and 13C NMR, IR, UV-vis and mass spectra." @default.
- W1972455054 created "2016-06-24" @default.
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- W1972455054 date "1993-09-01" @default.
- W1972455054 modified "2023-10-17" @default.
- W1972455054 title "The synthesis and characterization of novel dioximes and their heteronuclear complexes containing crown ether moieties" @default.
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- W1972455054 doi "https://doi.org/10.1016/s0277-5387(00)84371-5" @default.
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