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- W1972503350 abstract "Addition of the respective Lewis base donors PMDTA and HMPA to lithiated Schöllkopf's bis[lactim ether] (=3,6-diethoxy-2,5-dihydro-2-isopropylpyrazine) results in the formation of the monomeric PMDTA complex (R)-(4) (P212121, orthorhombic) and the dimeric HMPA complex (R,S)-3 (P, triclinic), as determined by single-crystal X-ray crystallography. Complex 3 was always found in racemic form, while complex 4 was enantiomerically pure. The racemization process that leads to the HMPA complex (R,S)-3 was investigated and found to be independent of the temperature at which either lithiation or addition of the Lewis base occurs." @default.
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- W1972503350 date "2002-10-01" @default.
- W1972503350 modified "2023-10-18" @default.
- W1972503350 title "Solid-State Structures and Racemization of Lithiated Schllkopf's Bis[Lactim Ether]" @default.
- W1972503350 doi "https://doi.org/10.1002/1522-2675(200210)85:10<3516::aid-hlca3516>3.0.co;2-w" @default.
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