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- W1972504841 abstract "Abstract Static 13C and 13C-{1H} NMR spectra of carbon-13 enriched methane (13CH4) adsorbed into SAPO-11 molecular sieve were recorded at variable temperatures. Moreover, the corresponding MAS NMR spectra were measured. These experiments reveal a temperature-dependent, anisotropic and asymmetric 13C nuclear shielding tensor. Ab initio model calculations of methane in the field of a positive point charge suggest that the deformation of the shielding tensor may be related to the interaction between the methane molecule and the charge-compensating protons. A comparison with existing Xe data is made." @default.
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- W1972504841 date "1996-10-01" @default.
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- W1972504841 title "13C NMR spectroscopy of methane adsorbed in SAPO-11 molecular sieve" @default.
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- W1972504841 doi "https://doi.org/10.1016/0009-2614(96)00996-7" @default.
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