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- W1972506947 abstract "Abstract The cathodic reduction of vanillin in aqueous solution on mercury electrode was studied. The product distributions were mainly dependent on compositions of electrolyte solution. The main products in strongly basic and neutral solutions were hydravanilloin and vanillyl alcohol, respectively. The electrocatalytic effect of sodium ion in the strongly basic solution was also investigated. The results indicated that sodium ion promoted the reduction and the reaction orders were dependent on the cathodic potential. The reaction mechanism was proposed and the reaction kinetics were analyzed. The experimental results and the theoretical analysis revealed that the rate determining step shifted from a chemical reaction step to an electrochemical reaction step when the cathodic potential changed from −1.65 to −1.80 V ( vs sce )." @default.
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- W1972506947 date "1987-02-01" @default.
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- W1972506947 title "Product distributions and kinetics of cathodic reduction of vanillin in aqueous solution" @default.
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- W1972506947 doi "https://doi.org/10.1016/0013-4686(87)85041-7" @default.
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