FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W1972555109> ?p ?o ?g. }

• W1972555109 endingPage "1662" @default.
• W1972555109 startingPage "1647" @default.
• W1972555109 abstract "The bis-bidentate ligand R , S -1,2-diphenyl- N , N' -bis(2-quinolinemethylidene)ethane-1,2-diamine (ligand 4 ), containing two (iminomethyl)quinoline moieties separated by a cis -1,2-diphenylethylene spacer, forms stable complexes with both Cu I and Cu II . With Cu II , the monomeric 1:1 complex [Cu II ( 4 )] 2+ is obtained both in CH 3 CN and CH 2 Cl 2 . With Cu I and overall 1:1 metal/ligand molar ratio, an equilibrium mixture is obtained in CH 3 CN, consisting of [Cu I ( 4 ) 2 ] + , [Cu I 2 ( 4 ) 2 ] 2+ and [Cu I 2 ( 4 )(CH 3 CN) 4 ] 2+ . The preponderant species is the two-metal one-ligand open complex [Cu I 2 ( 4 )(CH 3 CN) 4 ] 2+ , in which each Cu + cation is coordinated in a tetrahedral fashion by one (iminomethyl)quinoline unit and by two CH 3 CN molecules. Precipitation from the equilibrium mixture yields only crystals of [Cu I 2 ( 4 )(CH 3 CN) 4 ](ClO 4 ) 2 ·2CH 3 CN, whose crystal and molecular structures have been determined. On the other hand, in the poorly coordinating CH 2 Cl 2 solvent, only the dimeric helical [Cu I 2 ( 4 ) 2 ] 2+ complex is obtained, when the overall metal/ligand 1:1 molar ratio is chosen. Addition of large quantities of acetonitrile to solutions of [Cu I 2 ( 4 ) 2 ] 2+ in dichlorometane results in the formation of [Cu I 2 ( 4 )(CH 3 CN) 4 ] 2+ , i.e. in the solvent-driven disassembling of the Cu I helicate. While electrochemistry in CH 3 CN is poorly defined due to the presence of more than one Cu I species, cyclic voltammetry experiments carried out in CH 2 Cl 2 revealed a well defined behavior, with irreversible oxidation of [Cu I 2 ( 4 ) 2 ] 2+ and irreversible reduction of [Cu II ( 4 )] 2+ taking place at separate potentials (∆ E ≈ 700 mV). Irreversibility and separation of the redox events are due to the self-assembling and disassembling processes following the reduction and oxidation, respectively." @default.
• W1972555109 created "2016-06-24" @default.
• W1972555109 creator A5003298304 @default.
• W1972555109 creator A5016141032 @default.
• W1972555109 creator A5026297694 @default.
• W1972555109 creator A5039663296 @default.
• W1972555109 creator A5082658632 @default.
• W1972555109 date "2003-01-01" @default.
• W1972555109 modified "2023-10-16" @default.
• W1972555109 title "A Solvent-Dependent and Electrochemically Controlled Self-Assembling/Disassembling System" @default.
• W1972555109 cites W1539712552 @default.
• W1972555109 cites W1925105860 @default.
• W1972555109 cites W1969635440 @default.
• W1972555109 cites W1969767653 @default.
• W1972555109 cites W1971950282 @default.
• W1972555109 cites W1975318205 @default.
• W1972555109 cites W1980130900 @default.
• W1972555109 cites W1986276404 @default.
• W1972555109 cites W1991202124 @default.
• W1972555109 cites W2041560104 @default.
• W1972555109 cites W2055123588 @default.
• W1972555109 cites W2075745859 @default.
• W1972555109 cites W2085652318 @default.
• W1972555109 cites W2090130648 @default.
• W1972555109 cites W2093482748 @default.
• W1972555109 cites W2097473830 @default.
• W1972555109 cites W2105258065 @default.
• W1972555109 cites W2118902024 @default.
• W1972555109 cites W2122220082 @default.
• W1972555109 cites W2132956575 @default.
• W1972555109 doi "https://doi.org/10.1135/cccc20031647" @default.
• W1972555109 hasPublicationYear "2003" @default.
• W1972555109 type Work @default.
• W1972555109 sameAs 1972555109 @default.
• W1972555109 citedByCount "2" @default.
• W1972555109 crossrefType "journal-article" @default.
• W1972555109 hasAuthorship W1972555109A5003298304 @default.
• W1972555109 hasAuthorship W1972555109A5016141032 @default.
• W1972555109 hasAuthorship W1972555109A5026297694 @default.
• W1972555109 hasAuthorship W1972555109A5039663296 @default.
• W1972555109 hasAuthorship W1972555109A5082658632 @default.
• W1972555109 hasConcept C115624301 @default.
• W1972555109 hasConcept C116569031 @default.
• W1972555109 hasConcept C155647269 @default.
• W1972555109 hasConcept C166940927 @default.
• W1972555109 hasConcept C170493617 @default.
• W1972555109 hasConcept C178516000 @default.
• W1972555109 hasConcept C178790620 @default.
• W1972555109 hasConcept C185592680 @default.
• W1972555109 hasConcept C188027245 @default.
• W1972555109 hasConcept C2776309666 @default.
• W1972555109 hasConcept C2777463227 @default.
• W1972555109 hasConcept C2780471494 @default.
• W1972555109 hasConcept C2780871995 @default.
• W1972555109 hasConcept C32909587 @default.
• W1972555109 hasConcept C521977710 @default.
• W1972555109 hasConcept C544153396 @default.
• W1972555109 hasConcept C55493867 @default.
• W1972555109 hasConcept C8010536 @default.
• W1972555109 hasConceptScore W1972555109C115624301 @default.
• W1972555109 hasConceptScore W1972555109C116569031 @default.
• W1972555109 hasConceptScore W1972555109C155647269 @default.
• W1972555109 hasConceptScore W1972555109C166940927 @default.
• W1972555109 hasConceptScore W1972555109C170493617 @default.
• W1972555109 hasConceptScore W1972555109C178516000 @default.
• W1972555109 hasConceptScore W1972555109C178790620 @default.
• W1972555109 hasConceptScore W1972555109C185592680 @default.
• W1972555109 hasConceptScore W1972555109C188027245 @default.
• W1972555109 hasConceptScore W1972555109C2776309666 @default.
• W1972555109 hasConceptScore W1972555109C2777463227 @default.
• W1972555109 hasConceptScore W1972555109C2780471494 @default.
• W1972555109 hasConceptScore W1972555109C2780871995 @default.
• W1972555109 hasConceptScore W1972555109C32909587 @default.
• W1972555109 hasConceptScore W1972555109C521977710 @default.
• W1972555109 hasConceptScore W1972555109C544153396 @default.
• W1972555109 hasConceptScore W1972555109C55493867 @default.
• W1972555109 hasConceptScore W1972555109C8010536 @default.
• W1972555109 hasIssue "9" @default.
• W1972555109 hasLocation W19725551091 @default.
• W1972555109 hasOpenAccess W1972555109 @default.
• W1972555109 hasPrimaryLocation W19725551091 @default.
• W1972555109 hasRelatedWork W1966931665 @default.
• W1972555109 hasRelatedWork W1970358650 @default.
• W1972555109 hasRelatedWork W1984696380 @default.
• W1972555109 hasRelatedWork W1999947267 @default.
• W1972555109 hasRelatedWork W2012128185 @default.
• W1972555109 hasRelatedWork W2027078522 @default.
• W1972555109 hasRelatedWork W2076863134 @default.
• W1972555109 hasRelatedWork W2332841977 @default.
• W1972555109 hasRelatedWork W2739936718 @default.
• W1972555109 hasRelatedWork W34732219 @default.
• W1972555109 hasVolume "68" @default.
• W1972555109 isParatext "false" @default.
• W1972555109 isRetracted "false" @default.
• W1972555109 magId "1972555109" @default.
• W1972555109 workType "article" @default.