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- W1972566838 abstract "Abstract High-pressure mercury lamp irradiation of chiral alkyl glyoxylates [ R (−)-menthyl, R (−)- and S (+)-2-octyl, R (−)-and S (+)-2, 2-dimethyl-3-butyl] with furan led to alkyl 2,7-dioxabicyclo-[3.2.0] hept-3-ene-6-car☐ylates ( 13a–e ) exhibiting low (2.5–7.3%) optical purity. Compounds 13a–e were isomerized to alkyl 3-furylglycolates ( 14a–e ) in good yield. Configuration S was assigned to levorotary methyl 3-furlymethoxyacetate. Two interpretations of the results of asymmetric synthesis were proposed." @default.
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- W1972566838 date "1982-01-01" @default.
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- W1972566838 title "Asymmetric photocycloaddition between furan and chiral alkyl glyoxylates" @default.
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- W1972566838 doi "https://doi.org/10.1016/0040-4020(82)80228-7" @default.
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