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• W1972567488 abstract "We demonstrate significant photoresponsivity in aqueous media to visible light of pseudo-oligonucleotides possessing 4-(dimethylamino)azobenzene (4-DMAzo) side chains. The spectrum of the 4-DMAzo moiety during 436 nm light irradiation at pH >9 was clearly different from that of the all (E)-form, indicating the presence of the (Z)-form. Thermal (Z)-to-(E) recovery isomerization was faster at pH 9 (k Z -E = ∼101 s−1) than at pH 11; however, addition of 50% ethanol significantly slowed the thermal recovery isomerization at pH 9 (k Z -E = ∼2 s−1) and increased the magnitude of the spectral changes. Significant photoregulation of DNA hybridization by visible light was demonstrated under this condition." @default.
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• W1972567488 date "2009-01-05" @default.
• W1972567488 modified "2023-10-06" @default.
• W1972567488 title "Visible-Light Photocontrol of (<i>E</i>)/(<i>Z</i>) Isomerization of the 4-(Dimethylamino)azobenzene Pseudo-Nucleotide Unit Incorporated into an Oligonucleotide and DNA Hybridization in Aqueous Media" @default.
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• W1972567488 doi "https://doi.org/10.1080/15257770802581641" @default.
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