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• W1972569715 abstract "Abstract In this study, superposition model (SPM) is employed to investigate the local environment around the different Mn 2+ centers in ZnAl 2 S 4 spinel. Using SPM and crystallographic data, the zero-field splitting (ZFS) parameters b 2 0 , b 4 0 , and b 4 3 are calculated for Mn 2+ at the B-site (with local symmetry D 3d ), whereas b 4 0 and b 4 4 for the A-site ( T d ). The lattice relaxation due to Mn 2+ impurities is analyzed in terms of the bonding lengths and the angles between the Mn–S bond and the crystallographic axis [1 1 1]. Our SPM analysis of ZFS parameters indicates that satisfactory agreement can be achieved between the theoretical and the experimental results. Additional structural information about Mn 2+ impurity centers is also obtained." @default.
• W1972569715 created "2016-06-24" @default.
• W1972569715 creator A5062272780 @default.
• W1972569715 date "2009-10-01" @default.
• W1972569715 modified "2023-09-25" @default.
• W1972569715 title "Superposition model (SPM) analysis of zero-field splitting parameters of Mn2+ doped ZnAl2S4 crystal" @default.
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• W1972569715 doi "https://doi.org/10.1016/j.jpcs.2009.08.001" @default.
• W1972569715 hasPublicationYear "2009" @default.
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