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- W1972575427 abstract "Abstract We report the self‐consistent field theory (SCFT) of the morphology of lamella‐forming diblock copolymer thin films confined in two horizontal symmetrical/asymmetrical surfaces. The morphological dependences of thin films on the polymer‐surface interactions and confinement, such as film thickness and confinement spatial structure, have been systematically investigated. Mechanisms of the morphological transitions can be understood mainly through the polymer‐surface interactions and confinement entropy, in which the plat confinement surface provides a surface‐induced effect. The confinement is expressed in the form of the ratio D / L 0 , here D is film thickness, and L 0 is the period of bulk lamellar‐structure. Much richer morphologies and multiple surface‐induced morphological transitions for the lamella‐forming diblock copolymer thin films are observed, which have not been reported before. © 2008 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 47: 1–10, 2009" @default.
- W1972575427 created "2016-06-24" @default.
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- W1972575427 date "2008-11-24" @default.
- W1972575427 modified "2023-10-18" @default.
- W1972575427 title "Microdomain morphology of lamella-forming diblock copolymer confined in a thin film" @default.
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- W1972575427 doi "https://doi.org/10.1002/polb.21606" @default.
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