Matches in SemOpenAlex for { <https://semopenalex.org/work/W1972587060> ?p ?o ?g. }
- W1972587060 endingPage "2964" @default.
- W1972587060 startingPage "2958" @default.
- W1972587060 abstract "Reversible addition-fragmentation chain transfer (RAFT) polymerization was utilized to prepare multiresponsive, self-assembling amphiphilic poly[(N,N-dimethylaminoethyl methacrylate)x-b-(N-isopropylacrylamide)y] (DMAEMAx-b-NIPAMy). Controlling block lengths, solution pH, and NaCl concentration to elicit changes in the hydrophilic mass fraction resulted in specific morphological changes upon thermally induced assembly. At y = 102 (68 wt % DMAEMA), DMAEMA165-b-NIPAM102 copolymers self-assemble into simple core−shell micelles (58 nm). Increasing y to 202 (48 wt % DMAEMA) leads to a mixture of spherical micelles (78 nm) and worm-like micelles (D = 50−100 nm, L = 400−500 nm). Further increasing y to 435 (36 wt % DMAEMA) produces vesicular structures (179 nm). Significantly, reversible assembly of these nanostructures from the present stimuli-responsive diblock copolymers can be accomplished directly in aqueous media without the necessity of dialysis or manipulation with cosolvents. Additionally, the associated nanostructures can be shell cross-linked above the critical aggregation temperature via the in situ formation of gold nanoparticles yielding assemblies with long-term aqueous stability." @default.
- W1972587060 created "2016-06-24" @default.
- W1972587060 creator A5001808054 @default.
- W1972587060 creator A5007180693 @default.
- W1972587060 creator A5018763999 @default.
- W1972587060 creator A5055006496 @default.
- W1972587060 creator A5074998121 @default.
- W1972587060 creator A5082831418 @default.
- W1972587060 date "2009-03-24" @default.
- W1972587060 modified "2023-10-17" @default.
- W1972587060 title "Tuning Nanostructure Morphology and Gold Nanoparticle “Locking” of Multi-Responsive Amphiphilic Diblock Copolymers † Paper No. 138 in a series on Water Soluble Polymers." @default.
- W1972587060 cites W1963781924 @default.
- W1972587060 cites W1965534736 @default.
- W1972587060 cites W1967939236 @default.
- W1972587060 cites W1968219234 @default.
- W1972587060 cites W1970995940 @default.
- W1972587060 cites W1971731968 @default.
- W1972587060 cites W1975639265 @default.
- W1972587060 cites W1979509656 @default.
- W1972587060 cites W1979975654 @default.
- W1972587060 cites W1982318942 @default.
- W1972587060 cites W1984295293 @default.
- W1972587060 cites W1988129390 @default.
- W1972587060 cites W1989958800 @default.
- W1972587060 cites W1993964194 @default.
- W1972587060 cites W1995355528 @default.
- W1972587060 cites W1995759186 @default.
- W1972587060 cites W2000011083 @default.
- W1972587060 cites W2001528412 @default.
- W1972587060 cites W2001865610 @default.
- W1972587060 cites W2004276237 @default.
- W1972587060 cites W2005149525 @default.
- W1972587060 cites W2006539694 @default.
- W1972587060 cites W2008829575 @default.
- W1972587060 cites W2012134936 @default.
- W1972587060 cites W2012794705 @default.
- W1972587060 cites W2012996914 @default.
- W1972587060 cites W2013722538 @default.
- W1972587060 cites W2015587866 @default.
- W1972587060 cites W2018829581 @default.
- W1972587060 cites W2023814391 @default.
- W1972587060 cites W2024745369 @default.
- W1972587060 cites W2025040330 @default.
- W1972587060 cites W2033394479 @default.
- W1972587060 cites W2035722505 @default.
- W1972587060 cites W2037864161 @default.
- W1972587060 cites W2038063850 @default.
- W1972587060 cites W2041671510 @default.
- W1972587060 cites W2045573038 @default.
- W1972587060 cites W2049106847 @default.
- W1972587060 cites W2049844518 @default.
- W1972587060 cites W2052566608 @default.
- W1972587060 cites W2057068506 @default.
- W1972587060 cites W2062300034 @default.
- W1972587060 cites W2062867646 @default.
- W1972587060 cites W2067525170 @default.
- W1972587060 cites W2068297759 @default.
- W1972587060 cites W2070698780 @default.
- W1972587060 cites W2071423972 @default.
- W1972587060 cites W2071634878 @default.
- W1972587060 cites W2073112867 @default.
- W1972587060 cites W2074289058 @default.
- W1972587060 cites W2075116253 @default.
- W1972587060 cites W2076232279 @default.
- W1972587060 cites W2077228161 @default.
- W1972587060 cites W2081879892 @default.
- W1972587060 cites W2090151266 @default.
- W1972587060 cites W2091198938 @default.
- W1972587060 cites W2093410682 @default.
- W1972587060 cites W2095008840 @default.
- W1972587060 cites W2096455311 @default.
- W1972587060 cites W2104018884 @default.
- W1972587060 cites W2110950744 @default.
- W1972587060 cites W2121501788 @default.
- W1972587060 cites W2137002844 @default.
- W1972587060 cites W2137968700 @default.
- W1972587060 cites W2159200136 @default.
- W1972587060 cites W2161206448 @default.
- W1972587060 cites W2163328781 @default.
- W1972587060 cites W2170103495 @default.
- W1972587060 cites W2610367514 @default.
- W1972587060 cites W4211116566 @default.
- W1972587060 cites W4241409678 @default.
- W1972587060 cites W4317640765 @default.
- W1972587060 doi "https://doi.org/10.1021/ma802827p" @default.
- W1972587060 hasPublicationYear "2009" @default.
- W1972587060 type Work @default.
- W1972587060 sameAs 1972587060 @default.
- W1972587060 citedByCount "88" @default.
- W1972587060 countsByYear W19725870602012 @default.
- W1972587060 countsByYear W19725870602013 @default.
- W1972587060 countsByYear W19725870602014 @default.
- W1972587060 countsByYear W19725870602015 @default.
- W1972587060 countsByYear W19725870602016 @default.
- W1972587060 countsByYear W19725870602017 @default.
- W1972587060 countsByYear W19725870602018 @default.
- W1972587060 countsByYear W19725870602019 @default.
- W1972587060 countsByYear W19725870602020 @default.