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- W1972587285 abstract "Abstract The 1 H NMR spin-lattice relaxation time T 1 , 35 Cl NQR frequency ν Q , and 35 Cl NQR spin-lattice relaxation time T 1Q of [Zn(H 2 O) 6 ] [SnCl 6 ] (zinc hexachlorostannate(IV) hexahydrate) have been measured at temperatures between 77 and 350 K. The NQR spin echo signal with ν Q = 15.689 MHz at 77 K showed a positive temperature coefficient attributable to O-H-Cl type H-bonds in the crystal. ν Q at 77 K is strongly correlated with the electronegativity χ M of the metal M in the series of stannates [M(H 2 O) 6 ] [SnCl 6 ] (M = Mg, Ca, Mn, Co, Ni, Zn). A T 1 minimum observed for the Zn salt is ascribed to 180° flips of water molecules with an activation energy of 20 kJ mol -1 . The motion is influenced by repulsive forces among the water molecules within a cation rather than by attractive forces between the H-bonded H and CI atoms. T 1Q proved to be mainly governed by lattice vibrations, weakly modulated by the fluctuating electric field gradient caused by the 180° flip motions." @default.
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- W1972587285 date "1996-06-01" @default.
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- W1972587285 title "Motion of Water Molecules and Hydrogen Bonds in Zinc Hexachlorostannate (IV) Hexahydrate as Studied by 1H NMR and 35Cl NQR" @default.
- W1972587285 doi "https://doi.org/10.1515/zna-1996-5-654" @default.
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