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- W1972632082 abstract "Irradiation of the 3-azidoquinolines (6a-c) in the presence of sodium methoxide resulted in ring expansion to give the fully unsaturated 3-methoxy-3H-1, 4-benzodiazepines (8). Further treatment of the 2-unsubstituted 3H-1, 4-benzodiazepine (8a) with sodium methoxide in methanol gave the solvent adduct 7, which reverted to 8a on being refluxed in benzene, whereas the 2- substituted 3H-1, 4-benzodiazepines (8b, c), upon treatment with sodium methoxide, underwent tautomerization to afford the 5H-1, 4-benzodiazepines (15). Some reactions of the new 1, 4- benzodiazepines (8 and 15) thus obtained were also examined." @default.
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- W1972632082 date "1987-01-01" @default.
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- W1972632082 title "Studies on diazepines. XXIX. Syntheses of 3H- and 5H-1,4-benzodiazepines from 3-azidoquinolines." @default.
- W1972632082 doi "https://doi.org/10.1248/cpb.35.4110" @default.
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