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- W1972645301 abstract "The Dirac equation for H2+ is reduced to a form similar to that of the Schrödinger equation with some perturbation terms. A first-order perturbation calculation for the 1sσg state then reveals that these relativistic effects lower the electronic energy by a small amount of order 0.2α2 for most internuclear separations and thereby make the molecule slightly more stable. The formalism is readily generalized to the isoelectronic sequence of H2+, and the ratio of the relativistic correction to the nonrelativistic energy is found to be of order Z2α2. Consequently, the relativistic correction becomes progressively more important as Z increases." @default.
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- W1972645301 date "1969-02-15" @default.
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- W1972645301 title "Relativistic Theory of H2+" @default.
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- W1972645301 doi "https://doi.org/10.1063/1.1671253" @default.
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