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- W1972685290 abstract "Abstract Expressions are derived for the dielectric and mechanical base relaxation times of a polymer above its glass transition temperature. Coupled oscillator theory is invoked to show that a low-frequency dielectric relaxation should have a relaxation time proportional to the degree of polymerization, N . A damped linear array is used to calculate the base mechanical relaxation time, τ p . The principles of intermolecular forces and dielectric energy dissipation are taken from previous work of the author in order to model the frictional drag and elastic constants required by the equation of motion of the damped linear array. The relaxation time τ p is shown to be proportional to N 3.33 . Finally, τ p is used to develop the relation between zero-shear viscosity and molecular weight for a polymer melt, with polystyrene used as an example." @default.
- W1972685290 created "2016-06-24" @default.
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- W1972685290 date "1988-03-01" @default.
- W1972685290 modified "2023-09-25" @default.
- W1972685290 title "Dielectric and mechanical relaxation times of a polymer using intermolecular forces" @default.
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- W1972685290 doi "https://doi.org/10.1016/0032-3861(88)90375-8" @default.
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