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- W1972690604 abstract "[structure: see text] Prostaglandin H synthase catalyzes the first committed step in the biosynthesis of prostaglandins and thromboxane. Herein we report the synthesis of four site-specifically labeled arachidonic acids for investigation of the radical intermediate formed during this enzymatic reaction. Two compounds were prepared using a common C9-C11 fragment, while another target was synthesized using a previously reported advanced intermediate. An alkyne coupling followed by hydrogenation and Wittig reaction was used to prepare the final labeled substrate." @default.
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- W1972690604 date "2004-01-14" @default.
- W1972690604 modified "2023-09-27" @default.
- W1972690604 title "Synthesis of Site-Specifically Labeled Arachidonic Acids as Mechanistic Probes for Prostaglandin H Synthase" @default.
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- W1972690604 doi "https://doi.org/10.1021/ol0361711" @default.
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