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- W1972692015 abstract "Abstract A number of C 60 (CF 3 ) n compounds with n = 2–10 have been synthesized by the reaction of C 60 with silver trifluoroacetate and successfully isolated by means of HPLC. This resulted in the first crystal structure determination of six lower trifluoromethyl derivatives with n = 2 (single isomer), 4 (two isomers), and 6 (three isomers). A kinetic model of sequential trifluoromethylation based on the Bell–Evans–Polanyi principle has been used to explain the experimentally observed isomeric distribution in the mixtures of C 60 (CF 3 ) n compounds up to n = 6. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007)" @default.
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- W1972692015 date "2007-10-01" @default.
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- W1972692015 title "Synthesis, Structure, and Theoretical Study of Lower Trifluoromethyl Derivatives of [60]Fullerene" @default.
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- W1972692015 doi "https://doi.org/10.1002/ejoc.200700487" @default.
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