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- W1972698116 abstract "The equilibria for the synthesis of C2H5OC(CH3)3(A) and C2H5OC(CH3)2(C2H5) (B) from C2H5OH (C) and CH2:C(CH3)2(D) or CH3CH:C(CH3)2(E) in the liquid phase were investigated at temperatures from 313 K to 412 K. On the basis of experimental equilibrium constants found forn(C)/n(D) orn(C)/n(E) ≥ 4, the following values were obtained for ΔrHm°/(kJ·mol−1) and ΔrSm°/(J·K−1·mol−1): (C + D = A),−(35.45 ± 1.94) and −(82.37 ± 5.99); (C + A = B), −(34.13 ± 0.81) and −(87.82 ± 2.18). The following values of ΔfHm°(298.15 K)/(kJ·mol−1) have been derived: C2H5OC(CH3)3(1),−(350.8 ± 2.6); C2H5OC(CH3)2(C2H5)(1), −(379.8 ± 1.4)." @default.
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- W1972698116 date "1995-07-01" @default.
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- W1972698116 title "Enthalpies of formation of 2-methyl-2-ethoxypropane and 2-ethyl-2-ethoxypropane from equilibrium measurements" @default.
- W1972698116 doi "https://doi.org/10.1006/jcht.1995.0077" @default.
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