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- W1972718197 abstract "The addition of primary amines as solubilizing reagents for phthalocyaninatoiron complexes is shown to afford six-coordinate bis(amine)phthalocyaninato complexes, i.e., [Fe(amine)2(pc)] 2 (amine = decan-1-amine) and 3 (amine = benzylamine), with the two new N-donors occupying the trans-axial positions. The new complexes were characterized by extensive NMR measurements in THF solution. For complex 3 with the benzylamine ligand, the solid-state structure was determined by X-ray diffraction methods. Complex 2 is sufficiently labile in THF solution to exchange one amine ligand against CO (gas) affording an equilibrium mixture containing [Fe(amine)(CO)(pc)] 4." @default.
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- W1972718197 date "2006-08-01" @default.
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- W1972718197 title "Solution NMR and X-Ray Structural Studies on Phthalocyaninatoiron Complexes" @default.
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- W1972718197 doi "https://doi.org/10.1002/hlca.200690153" @default.
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