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- W1972724716 abstract "SiC materials with tailored porosity and integrated Ni NPs (Ni@SiC) were synthesized via microphase separation of polycarbosilane-block-polyethylene followed by its pyrolysis. Changing the length of organic block allowed the synthesis of micro, meso and hierarchical Ni@SiC materials which were characterized by PXRD, TEM, TGA, and nitrogen physisorption. Selective hydrogenolysis of aryl ethers mimicking the most abundant linkages of lignin was achieved in water avoiding the possible hydrogenation of aromatic rings. The sustainable production of fine chemicals and fuels from re- newable resources is a burgeoning and challenging research area. (1) Lignocellulose biomass (cellulose, hemi-cellulose and lignin) is a key resource whose availability is plentiful and its utilisation will allay the fears regarding competition with food supplies. (1, 2) Although cellulose can be depolymerised in many ways, (3) selective cleavage of aryl ether (CArO) and especially diaryl ether substructures of lignin is challenging. (4) Lignin con- stitutes 15-30 % of woody biomass (5) with an energy content of up to 40 % of this biomass (6) and its selective depolymerisa- tion (through hydrogenolysis) is crucial for the generation of fuel and chemicals from renewable resources. Selective cleav- age of the CArO bond of lignin model compounds in organic solvents has been reported by the use of molecular catalysts (V, (7) Ru (8) and Ni (9) complexes) and heterogeneous catalysts" @default.
- W1972724716 created "2016-06-24" @default.
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- W1972724716 date "2013-10-21" @default.
- W1972724716 modified "2023-10-12" @default.
- W1972724716 title "Robust Heterogeneous Nickel Catalysts with Tailored Porosity for the Selective Hydrogenolysis of Aryl Ethers" @default.
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- W1972724716 doi "https://doi.org/10.1002/cctc.201300763" @default.
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