Matches in SemOpenAlex for { <https://semopenalex.org/work/W1972777545> ?p ?o ?g. }
Showing items 1 to 86 of
86
with 100 items per page.
- W1972777545 abstract "A new method to generate chiral cis-vinyloxiranes from readily available starting materials is reported. (α-Chloroallyl)lithium, generated in situ from LiN(c-Hex)2 and allyl chloride at −95°C, reacts with (−)-β-methoxydiisopinocampheylborane, dIpc2BOMe, to give an ate complex. Treatment of this with BF3·OEt2 leads to the reagent, [(Z)-γ-chloroallyl]BIpc2. Chloroallylboration of aldehydes using the latter reagent followed by elimination of chiral auxiliary provides syn-α-chlorohydrins in high de (≥94%) and ee (90–99%). Base-induced cyclization of chlorohydrins furnishes chiral cis-vinyloxiranes." @default.
- W1972777545 created "2016-06-24" @default.
- W1972777545 creator A5006742407 @default.
- W1972777545 creator A5036416611 @default.
- W1972777545 creator A5042692218 @default.
- W1972777545 date "1995-07-01" @default.
- W1972777545 modified "2023-09-27" @default.
- W1972777545 title "New access to chiral syn-α-Chlorohydrins and cis-vinyloxiranes through chloroallyboration" @default.
- W1972777545 cites W1491183344 @default.
- W1972777545 cites W1506938930 @default.
- W1972777545 cites W1978257757 @default.
- W1972777545 cites W1985730697 @default.
- W1972777545 cites W1986873657 @default.
- W1972777545 cites W1990865703 @default.
- W1972777545 cites W1995327968 @default.
- W1972777545 cites W2008059933 @default.
- W1972777545 cites W2035968398 @default.
- W1972777545 cites W2043554130 @default.
- W1972777545 cites W2047237547 @default.
- W1972777545 cites W2072413168 @default.
- W1972777545 cites W2091182886 @default.
- W1972777545 cites W2094676484 @default.
- W1972777545 cites W2136120481 @default.
- W1972777545 cites W2140465611 @default.
- W1972777545 cites W2950639005 @default.
- W1972777545 cites W2951017552 @default.
- W1972777545 cites W2951475477 @default.
- W1972777545 cites W2953326011 @default.
- W1972777545 doi "https://doi.org/10.1016/0040-4039(95)00928-6" @default.
- W1972777545 hasPublicationYear "1995" @default.
- W1972777545 type Work @default.
- W1972777545 sameAs 1972777545 @default.
- W1972777545 citedByCount "3" @default.
- W1972777545 crossrefType "journal-article" @default.
- W1972777545 hasAuthorship W1972777545A5006742407 @default.
- W1972777545 hasAuthorship W1972777545A5036416611 @default.
- W1972777545 hasAuthorship W1972777545A5042692218 @default.
- W1972777545 hasConcept C134018914 @default.
- W1972777545 hasConcept C134306372 @default.
- W1972777545 hasConcept C155647269 @default.
- W1972777545 hasConcept C178790620 @default.
- W1972777545 hasConcept C185592680 @default.
- W1972777545 hasConcept C2778541603 @default.
- W1972777545 hasConcept C2778695967 @default.
- W1972777545 hasConcept C33923547 @default.
- W1972777545 hasConcept C40875361 @default.
- W1972777545 hasConcept C42058472 @default.
- W1972777545 hasConcept C71924100 @default.
- W1972777545 hasConceptScore W1972777545C134018914 @default.
- W1972777545 hasConceptScore W1972777545C134306372 @default.
- W1972777545 hasConceptScore W1972777545C155647269 @default.
- W1972777545 hasConceptScore W1972777545C178790620 @default.
- W1972777545 hasConceptScore W1972777545C185592680 @default.
- W1972777545 hasConceptScore W1972777545C2778541603 @default.
- W1972777545 hasConceptScore W1972777545C2778695967 @default.
- W1972777545 hasConceptScore W1972777545C33923547 @default.
- W1972777545 hasConceptScore W1972777545C40875361 @default.
- W1972777545 hasConceptScore W1972777545C42058472 @default.
- W1972777545 hasConceptScore W1972777545C71924100 @default.
- W1972777545 hasLocation W19727775451 @default.
- W1972777545 hasOpenAccess W1972777545 @default.
- W1972777545 hasPrimaryLocation W19727775451 @default.
- W1972777545 hasRelatedWork W1972585666 @default.
- W1972777545 hasRelatedWork W1974765967 @default.
- W1972777545 hasRelatedWork W1976526162 @default.
- W1972777545 hasRelatedWork W1981388197 @default.
- W1972777545 hasRelatedWork W1985730697 @default.
- W1972777545 hasRelatedWork W2043660325 @default.
- W1972777545 hasRelatedWork W2070927862 @default.
- W1972777545 hasRelatedWork W2074513781 @default.
- W1972777545 hasRelatedWork W2104081863 @default.
- W1972777545 hasRelatedWork W2113317743 @default.
- W1972777545 hasRelatedWork W2161626899 @default.
- W1972777545 hasRelatedWork W2166571925 @default.
- W1972777545 hasRelatedWork W2949700273 @default.
- W1972777545 hasRelatedWork W2949914523 @default.
- W1972777545 hasRelatedWork W2950731154 @default.
- W1972777545 hasRelatedWork W2950926156 @default.
- W1972777545 hasRelatedWork W2951475477 @default.
- W1972777545 hasRelatedWork W2951585006 @default.
- W1972777545 hasRelatedWork W2953377663 @default.
- W1972777545 hasRelatedWork W2337960125 @default.
- W1972777545 isParatext "false" @default.
- W1972777545 isRetracted "false" @default.
- W1972777545 magId "1972777545" @default.
- W1972777545 workType "article" @default.