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• W1972789853 startingPage "2124" @default.
• W1972789853 abstract "We report an efficient method for the alkylation of γ-C(sp3)–H bonds of picolinamide-protected aliphatic amine substrates with primary alkyl iodides via palladium catalysis. Ag2CO3 and dibenzyl phosphate, (BnO)2PO2H, are critical promoters of this reaction. These reactions provide a convenient and straightforward method for the preparation of high-value N-containing products from readily available amine and alkyl iodide precursors." @default.
• W1972789853 created "2016-06-24" @default.
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• W1972789853 date "2013-01-29" @default.
• W1972789853 modified "2023-10-18" @default.
• W1972789853 title "Palladium-Catalyzed Picolinamide-Directed Alkylation of Unactivated C(sp³)–H Bonds with Alkyl Iodides" @default.
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• W1972789853 doi "https://doi.org/10.1021/ja312277g" @default.
• W1972789853 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/23350845" @default.
• W1972789853 hasPublicationYear "2013" @default.
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