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- W1972814897 abstract "The singlet excited-state lifetime of a terpyridyl platinum(II) pentynyl complex was determined to be 268+/-87 ps by fitting femtosecond transient absorption data, the triplet excited-state lifetime was found to be 62 ns by fitting nanosecond transient absorption decay data, and the triplet quantum yield was measured to be 0.16. A ground-state absorption cross section of 2.5 x 10(-19) cm(2) at 532 nm was deduced from UV-vis absorption data. Excited-state absorption cross sections of 3.5 x 10(-17) cm(2) (singlet) and 4.5 x 10(-17) cm(2) (triplet) were obtained by using a five-level dynamic model to fit open-aperture Z scans at picosecond and nanosecond pulse widths and a variety of pulse energies." @default.
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- W1972814897 date "2008-05-08" @default.
- W1972814897 modified "2023-10-17" @default.
- W1972814897 title "Excited-state absorption in a terpyridyl platinum(II) pentynyl complex" @default.
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- W1972814897 doi "https://doi.org/10.1364/ol.33.001053" @default.
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