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• W1972824863 abstract "Abstract We report on the electronic structure, electric transport and basic thermodynamic properties of the skutterudite-related Ce3Ru4Sn13 and La3Ru4Sn13. The calculated density of electronic states within the local spin density approximation (LSDA) method well fit the X-ray photoelectron spectroscopy (XPS) valence band spectra of Ce3Ru4Sn13. Magnetic susceptibility and specific heat measurements reveal that the sixfold degenerated multiplet of Ce3+ ions splits into three doublets, due to the tetragonal Ce point local symmetry in the cubic Ce3Ru4Sn13 system. Ce3Ru4Sn13 exhibits a large increase in the specific heat, C / T , data due to Kondo effect and strong electron and short-range magnetic correlations, we also suggest significant contribution of the crystal field effect. La3Ru4Sn13 is typical BCS superconductor, however, specific heat and electrical resistivity data show that La3Ru4Sn13 also exhibits a second superconducting phase at higher temperatures, which is characteristic of inhomogeneous superconductors." @default.
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• W1972824863 date "2014-12-01" @default.
• W1972824863 modified "2023-10-16" @default.
• W1972824863 title "Crystal electric field and the ground state properties of heavy fermion Ce 3 Ru 4 Sn 13" @default.
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• W1972824863 doi "https://doi.org/10.1016/j.jallcom.2014.07.051" @default.
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