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• W1972851941 startingPage "3067" @default.
• W1972851941 abstract "Methanol adsorption into the porous 2D bimetallic coordination network {[Ni(cyclam)](3)[W(CN)(8)](2)}(n) (cyclam = 1,4,8,11-tetraazacyclotetradecane) causes significant modification of its structure and magnetic properties. Fully reversible transformations between the three states of the network: anhydrous, hydrated and methanol-modified are observed with the transition to the magnetic ordered state at T(c) equal to 4.9 K, 8.3 K and 11.4 K respectively. All three phases have a metamagnetic character but the methanol-modified one most easily turns to ferromagnetic and shows a hysteresis loop with coercivity field of 250 Oe. The differences in magnetic behaviour of the anhydrous and guest-induced forms of the compound are discussed in terms of changes in the structure: CN-bridge geometry and distance between the layers." @default.
• W1972851941 created "2016-06-24" @default.
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• W1972851941 date "2011-01-01" @default.
• W1972851941 modified "2023-10-15" @default.
• W1972851941 title "Microporous {[Ni(cyclam)]3[W(CN)8]2}n affording reversible structural and magnetic conversions" @default.
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• W1972851941 doi "https://doi.org/10.1039/c0dt01434f" @default.
• W1972851941 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/21331398" @default.
• W1972851941 hasPublicationYear "2011" @default.
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