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• W1972863721 abstract "Silyl-inspired spirocycle: The title reaction is the first example of a catalytic asymmetric [3+2] annulation reaction with allylsilanes. The annulation reaction utilizes a chiral ScCl2(SbF6)/L catalyst and TMSCl as a promoter to afford spirooxindoles in excellent enantioselectivity at room temperature. The SiC bond can be oxidized to deliver hydroxy-substituted spirooxindoles. TMS=trimethylsilyl." @default.
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• W1972863721 date "2011-12-12" @default.
• W1972863721 modified "2023-10-02" @default.
• W1972863721 title "Catalytic Asymmetric [3+2] Annulation of Allylsilanes with Isatins: Synthesis of Spirooxindoles" @default.
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• W1972863721 doi "https://doi.org/10.1002/anie.201105739" @default.
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