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• W1972924550 abstract "Abstract The swelling of a layered protonic titanate H0.7Ti1.825 □0.175O4 · H2O (□:vacancy) upon contact with the system of tetrabutylammonium (TBA) ion and H2O has been studied by X-ray diffraction. The TBA-intercalated titanate revealed three distinct gallery heights of 1.47, 1.75 and 2.1 nm, depending on water vapor pressure and drying temperature. These are attributable to crystalline swelling, i. e., zero-, mono-and bi-layer hydrates. A much higher degree of hydration was discerned by a series of sharp diffraction lines for a colloidal aggregate centrifuged from an aqueous suspension of the titanate and TBA ion. The basal spacing expanded steadily from 4 to >20 nm with decrease of the TBA concentration. Along this osmotic swelling process, amorphouslike halo was evolved, which suggests exfoliation into single sheets." @default.
• W1972924550 created "2016-06-24" @default.
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• W1972924550 date "1998-03-01" @default.
• W1972924550 modified "2023-09-26" @default.
• W1972924550 title "X-Ray Diffraction Study on Crystalline and Osmotic Swelling of a Layered Titanate" @default.
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• W1972924550 doi "https://doi.org/10.1080/10587259808042419" @default.
• W1972924550 hasPublicationYear "1998" @default.
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