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- W1972934384 abstract "Abstract A solid-state electrochemical sensor for measuring SO X in a gas mixture has been designed by incorporating Na 3 Zr 2 Si 2 PO 12 (Nasicon) and (8 mol% Y 2 O 3 )-ZrO 2 (YSZ) as a solid electrolyte couple. The solid electrolyte couple consisted of 2-mm-thick sintered disk of Na 3 Zr 2 Si 2 PO 12 and a thin film of (8 mol% Y 2 O 3 ) ZrO 2 approximately 6 μm thick. YSZ thin film on Nasicon disk was prepared by multiple radio frequency (RF) magnetron sputtering technique. The sensor employs Na 2 SO 4 as an auxiliary or sensing electrode that is in contact with Nasicon. The SO 2 present in the gas mixture is converted to SO 3 by passing over heated Pt-catalyst. The sensor has been successfully tested in the laboratory environment. At a fixed concentration of 1000 ppm SO 2 , the electromotive force (emf) of the sensor was found to vary nonlinearly as a function of temperature between 823 and 1123 K. However, at a fixed temperature of 973 and 1023 K, the measured emf of the sensor was found to vary linearly as a function of the logarithm of concentration of SO X in the gas mixture between 100 and 3000 ppm. In the current sensor design, both electrodes are exposed to the same test gas eliminating the need for isolating the electrode compartments." @default.
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- W1972934384 date "2003-07-01" @default.
- W1972934384 modified "2023-10-13" @default.
- W1972934384 title "Planar SOX sensor incorporating a bi-electrolyte couple" @default.
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- W1972934384 doi "https://doi.org/10.1016/s0167-2738(03)00213-3" @default.
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