Matches in SemOpenAlex for { <https://semopenalex.org/work/W1972984906> ?p ?o ?g. }
Showing items 1 to 70 of
70
with 100 items per page.
- W1972984906 endingPage "505" @default.
- W1972984906 startingPage "499" @default.
- W1972984906 abstract "Though the treatment of ionic dissociation by thermodynamic methods has been fruitful, the mechanism can be better understood by the use of statistical mechanics. For this purpose one needs to know the potential energy of the ions as a function of temperature. The work D required to dissociate a molecule or molecular ion consists of two parts, one part Del due to electrostatic forces, and the other Dnon due to nonelectrostatic forces. As the former varies rapidly with temperature, for each species the value of dD/dT is a guide to the value of Del. It is shown that for acid molecules and molecular ions in aqueous solution the relative values of dD/dT for different types are in the order predicted. Further, the characteristic temperature θ at which the dissociation constant passes through a maximum should depend, not on the value of D, but on the relative magnitudes of Dnon and Del. It is found that the known values of θ fall into line in accordance with this rule. Between two Hg+ ions, or two Te— ions, there will be exchange forces of attraction similar to those which give rise to the molecules Na2 and Br2; thus in aqueous solution the ions (Hg2)++ and (Te2)—— are stable, although for them Del is negative." @default.
- W1972984906 created "2016-06-24" @default.
- W1972984906 creator A5034739170 @default.
- W1972984906 date "1938-09-01" @default.
- W1972984906 modified "2023-10-16" @default.
- W1972984906 title "Exchange Forces and Electrostatic Forces Between Ions in Solution" @default.
- W1972984906 cites W1965736404 @default.
- W1972984906 cites W2009038447 @default.
- W1972984906 cites W2135313387 @default.
- W1972984906 cites W2320567012 @default.
- W1972984906 cites W2322381517 @default.
- W1972984906 cites W2323693130 @default.
- W1972984906 cites W2324777999 @default.
- W1972984906 cites W27727037 @default.
- W1972984906 doi "https://doi.org/10.1063/1.1750301" @default.
- W1972984906 hasPublicationYear "1938" @default.
- W1972984906 type Work @default.
- W1972984906 sameAs 1972984906 @default.
- W1972984906 citedByCount "33" @default.
- W1972984906 crossrefType "journal-article" @default.
- W1972984906 hasAuthorship W1972984906A5034739170 @default.
- W1972984906 hasConcept C102931765 @default.
- W1972984906 hasConcept C117626034 @default.
- W1972984906 hasConcept C121332964 @default.
- W1972984906 hasConcept C145148216 @default.
- W1972984906 hasConcept C147789679 @default.
- W1972984906 hasConcept C159467904 @default.
- W1972984906 hasConcept C178790620 @default.
- W1972984906 hasConcept C184651966 @default.
- W1972984906 hasConcept C184779094 @default.
- W1972984906 hasConcept C185592680 @default.
- W1972984906 hasConcept C18762648 @default.
- W1972984906 hasConcept C2182769 @default.
- W1972984906 hasConcept C32909587 @default.
- W1972984906 hasConcept C97355855 @default.
- W1972984906 hasConceptScore W1972984906C102931765 @default.
- W1972984906 hasConceptScore W1972984906C117626034 @default.
- W1972984906 hasConceptScore W1972984906C121332964 @default.
- W1972984906 hasConceptScore W1972984906C145148216 @default.
- W1972984906 hasConceptScore W1972984906C147789679 @default.
- W1972984906 hasConceptScore W1972984906C159467904 @default.
- W1972984906 hasConceptScore W1972984906C178790620 @default.
- W1972984906 hasConceptScore W1972984906C184651966 @default.
- W1972984906 hasConceptScore W1972984906C184779094 @default.
- W1972984906 hasConceptScore W1972984906C185592680 @default.
- W1972984906 hasConceptScore W1972984906C18762648 @default.
- W1972984906 hasConceptScore W1972984906C2182769 @default.
- W1972984906 hasConceptScore W1972984906C32909587 @default.
- W1972984906 hasConceptScore W1972984906C97355855 @default.
- W1972984906 hasIssue "9" @default.
- W1972984906 hasLocation W19729849061 @default.
- W1972984906 hasOpenAccess W1972984906 @default.
- W1972984906 hasPrimaryLocation W19729849061 @default.
- W1972984906 hasRelatedWork W1548038933 @default.
- W1972984906 hasRelatedWork W1629940605 @default.
- W1972984906 hasRelatedWork W1999249120 @default.
- W1972984906 hasRelatedWork W2010049163 @default.
- W1972984906 hasRelatedWork W2028017161 @default.
- W1972984906 hasRelatedWork W2055983026 @default.
- W1972984906 hasRelatedWork W2100285875 @default.
- W1972984906 hasRelatedWork W2414102051 @default.
- W1972984906 hasRelatedWork W368608906 @default.
- W1972984906 hasRelatedWork W4297839670 @default.
- W1972984906 hasVolume "6" @default.
- W1972984906 isParatext "false" @default.
- W1972984906 isRetracted "false" @default.
- W1972984906 magId "1972984906" @default.
- W1972984906 workType "article" @default.