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- W1972989125 abstract "We have synthesized monoclinic mercury tungstate $({text{HgWO}}_{4})$ and characterized its structural and vibrational properties at room conditions. Additionally, we report the structural and lattice dynamical behavior of ${text{HgWO}}_{4}$ under high pressure studied by means of x-ray diffraction and Raman-scattering measurements up to 16 GPa and 25 GPa, respectively. The pressure dependence of the structural parameters and Raman-active first-order phonons of monoclinic $C2/c$ ${text{HgWO}}_{4}$ are discussed in the light of our theoretical first-principles total-energy and lattice dynamics calculations. Our measurements show that the monoclinic phase of ${text{HgWO}}_{4}$ is stable up to the maximum pressure reached in these experiments. Theoretically predicted possible high-pressure phases and the theoretical pressure dependence of infrared-active modes are also reported." @default.
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- W1972989125 date "2010-07-23" @default.
- W1972989125 modified "2023-10-18" @default.
- W1972989125 title "High-pressure structural and lattice dynamical study ofHgWO4" @default.
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- W1972989125 doi "https://doi.org/10.1103/physrevb.82.035212" @default.
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