Matches in SemOpenAlex for { <https://semopenalex.org/work/W1973005785> ?p ?o ?g. }
- W1973005785 endingPage "954" @default.
- W1973005785 startingPage "948" @default.
- W1973005785 abstract "Enantioselectivity in the (salen)Mn-catalyzed asymmetric epoxidation reaction correlates directly with the electronic properties of the ligand substituents, with complexes bearing electron-donating substituents affording highest ee's. Several lines of evidence point to a single factorcontrol of the position of the transition state along the reaction coordinateas being responsible for the electronic effects on enantioselectivity. Analysis of the epoxidation of cis-β-deuteriostyrene reveals that electron-rich catalysts display a more pronounced secondary inverse isotope effect than electron-deficient catalysts. A strong correlation between ΔΔH⧧ and the electronic character of the catalyst is also observed. The conclusion that enantioselectivity is tied to the position of a transition state along the reaction coordinate may hold general implications for the design of asymmetric catalysts, particularly those that effect reactions without substrate precoordination." @default.
- W1973005785 created "2016-06-24" @default.
- W1973005785 creator A5026276151 @default.
- W1973005785 creator A5030216985 @default.
- W1973005785 creator A5033171116 @default.
- W1973005785 creator A5034339797 @default.
- W1973005785 creator A5037736695 @default.
- W1973005785 creator A5040549961 @default.
- W1973005785 date "1998-01-08" @default.
- W1973005785 modified "2023-10-02" @default.
- W1973005785 title "The Mechanistic Basis for Electronic Effects on Enantioselectivity in the (salen)Mn(III)-Catalyzed Epoxidation Reaction" @default.
- W1973005785 cites W1969585810 @default.
- W1973005785 cites W1970663919 @default.
- W1973005785 cites W1972078993 @default.
- W1973005785 cites W1972493830 @default.
- W1973005785 cites W1976110704 @default.
- W1973005785 cites W1977196046 @default.
- W1973005785 cites W1980478926 @default.
- W1973005785 cites W1981674798 @default.
- W1973005785 cites W1983346165 @default.
- W1973005785 cites W1988946448 @default.
- W1973005785 cites W1989846616 @default.
- W1973005785 cites W2002508888 @default.
- W1973005785 cites W2011782223 @default.
- W1973005785 cites W2026766028 @default.
- W1973005785 cites W2036099524 @default.
- W1973005785 cites W2036859000 @default.
- W1973005785 cites W2037267833 @default.
- W1973005785 cites W2039939220 @default.
- W1973005785 cites W2048685361 @default.
- W1973005785 cites W2058246461 @default.
- W1973005785 cites W2065001988 @default.
- W1973005785 cites W2074960707 @default.
- W1973005785 cites W2084699035 @default.
- W1973005785 cites W2119837899 @default.
- W1973005785 cites W2122270648 @default.
- W1973005785 cites W2128259531 @default.
- W1973005785 cites W2144039247 @default.
- W1973005785 cites W2161314554 @default.
- W1973005785 cites W2949666687 @default.
- W1973005785 cites W2951021425 @default.
- W1973005785 cites W2951309128 @default.
- W1973005785 cites W2951609431 @default.
- W1973005785 cites W2951736118 @default.
- W1973005785 cites W2952567810 @default.
- W1973005785 cites W2953011238 @default.
- W1973005785 cites W2953349320 @default.
- W1973005785 doi "https://doi.org/10.1021/ja973468j" @default.
- W1973005785 hasPublicationYear "1998" @default.
- W1973005785 type Work @default.
- W1973005785 sameAs 1973005785 @default.
- W1973005785 citedByCount "377" @default.
- W1973005785 countsByYear W19730057852012 @default.
- W1973005785 countsByYear W19730057852013 @default.
- W1973005785 countsByYear W19730057852014 @default.
- W1973005785 countsByYear W19730057852015 @default.
- W1973005785 countsByYear W19730057852016 @default.
- W1973005785 countsByYear W19730057852017 @default.
- W1973005785 countsByYear W19730057852018 @default.
- W1973005785 countsByYear W19730057852019 @default.
- W1973005785 countsByYear W19730057852020 @default.
- W1973005785 countsByYear W19730057852021 @default.
- W1973005785 countsByYear W19730057852022 @default.
- W1973005785 countsByYear W19730057852023 @default.
- W1973005785 crossrefType "journal-article" @default.
- W1973005785 hasAuthorship W1973005785A5026276151 @default.
- W1973005785 hasAuthorship W1973005785A5030216985 @default.
- W1973005785 hasAuthorship W1973005785A5033171116 @default.
- W1973005785 hasAuthorship W1973005785A5034339797 @default.
- W1973005785 hasAuthorship W1973005785A5037736695 @default.
- W1973005785 hasAuthorship W1973005785A5040549961 @default.
- W1973005785 hasConcept C106773901 @default.
- W1973005785 hasConcept C111368507 @default.
- W1973005785 hasConcept C116569031 @default.
- W1973005785 hasConcept C121332964 @default.
- W1973005785 hasConcept C127313418 @default.
- W1973005785 hasConcept C146686406 @default.
- W1973005785 hasConcept C147597530 @default.
- W1973005785 hasConcept C161790260 @default.
- W1973005785 hasConcept C170493617 @default.
- W1973005785 hasConcept C178790620 @default.
- W1973005785 hasConcept C18553476 @default.
- W1973005785 hasConcept C185592680 @default.
- W1973005785 hasConcept C2777289219 @default.
- W1973005785 hasConcept C41339378 @default.
- W1973005785 hasConcept C55493867 @default.
- W1973005785 hasConcept C58364064 @default.
- W1973005785 hasConcept C62520636 @default.
- W1973005785 hasConcept C69928629 @default.
- W1973005785 hasConcept C71240020 @default.
- W1973005785 hasConcept C75473681 @default.
- W1973005785 hasConceptScore W1973005785C106773901 @default.
- W1973005785 hasConceptScore W1973005785C111368507 @default.
- W1973005785 hasConceptScore W1973005785C116569031 @default.
- W1973005785 hasConceptScore W1973005785C121332964 @default.
- W1973005785 hasConceptScore W1973005785C127313418 @default.
- W1973005785 hasConceptScore W1973005785C146686406 @default.
- W1973005785 hasConceptScore W1973005785C147597530 @default.