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- W1973009571 abstract "Abstract (ω-1)-Fluoroalkan-ω-olides 3 of medium to garge ring size can easily be synthesised in a facile two-step procedure by bromofluorination of terminally unsaturated fatty acids 1 with NBS/Et3N·3HF and subsequent cyclisation with K2CO3 in dimethyl sulfoxide. Electronic and conformational changes induced by the vicinal fluorine substituent in the transition state of SN2-cyclisation step (calculated by the AM1-method) were found to be responsible for a certainly hindered cyclisation of the monofluorinated compounds 2 in comparison with their non-fluorinated analogues." @default.
- W1973009571 created "2016-06-24" @default.
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- W1973009571 date "2010-08-05" @default.
- W1973009571 modified "2023-09-25" @default.
- W1973009571 title "ChemInform Abstract: A Facile Two-Step Synthesis of (ω-1)-Fluoroalkan-ω-olides. Influence of a Vicinal Fluorine Substituent in Nucleophilic Substitutions." @default.
- W1973009571 cites W2950930380 @default.
- W1973009571 doi "https://doi.org/10.1002/chin.199630213" @default.
- W1973009571 hasPublicationYear "2010" @default.
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