Matches in SemOpenAlex for { <https://semopenalex.org/work/W1973029228> ?p ?o ?g. }
- W1973029228 endingPage "1580" @default.
- W1973029228 startingPage "1569" @default.
- W1973029228 abstract "A microscopic theory of outersphere electron transfer reactions in electrolyte solutions is presented. Both static and dynamic effects of solvent and ion atmosphere on rates of electron transfer are calculated by employing molecular models. The donor–acceptor system is composed of two spheres and the electrolyte solution is composed of dipolar solvent molecules and ions which are treated at the same molecular level. A microscopic expression for the free energy of activation is derived by using density functional theory. The dynamic effects are calculated by using a molecular hydrodynamic theory which properly includes finite wave vector modes of relaxation of solvent and ion atmosphere. Explicit numerical results are presented for the activation free energy and the rate constant of electron transfer in solutions of varying ion concentration. It is found that ion atmosphere can make an important contribution to the activation free energy at finite ion concentration although the net increase in the activation energy is not very significant for the solutions studied in this work. This happens because, with increase of ion concentration, the ion atmosphere contribution to the total activation free energy increases, whereas the solvent contribution shows a decreasing trend. The solvent behaves as an effective less polar medium due to screening by ions and, therefore, its contribution to the activation free energy decreases as ion concentration is increased." @default.
- W1973029228 created "2016-06-24" @default.
- W1973029228 creator A5055636861 @default.
- W1973029228 date "1999-01-15" @default.
- W1973029228 modified "2023-10-06" @default.
- W1973029228 title "A theoretical study of outersphere electron transfer reactions in electrolyte solutions" @default.
- W1973029228 cites W1964467716 @default.
- W1973029228 cites W1964749921 @default.
- W1973029228 cites W1967979368 @default.
- W1973029228 cites W1970366261 @default.
- W1973029228 cites W1972625236 @default.
- W1973029228 cites W1974727943 @default.
- W1973029228 cites W1977983141 @default.
- W1973029228 cites W1978100566 @default.
- W1973029228 cites W1983663688 @default.
- W1973029228 cites W1986887211 @default.
- W1973029228 cites W2001270915 @default.
- W1973029228 cites W2001789729 @default.
- W1973029228 cites W2007772297 @default.
- W1973029228 cites W2008631597 @default.
- W1973029228 cites W2020003535 @default.
- W1973029228 cites W2020084711 @default.
- W1973029228 cites W2020574741 @default.
- W1973029228 cites W2021970904 @default.
- W1973029228 cites W2022690219 @default.
- W1973029228 cites W2022849802 @default.
- W1973029228 cites W2023739585 @default.
- W1973029228 cites W2023943543 @default.
- W1973029228 cites W2028140444 @default.
- W1973029228 cites W2029938911 @default.
- W1973029228 cites W2031866286 @default.
- W1973029228 cites W2032259304 @default.
- W1973029228 cites W2032341384 @default.
- W1973029228 cites W2036610165 @default.
- W1973029228 cites W2036656907 @default.
- W1973029228 cites W2038587572 @default.
- W1973029228 cites W2042254240 @default.
- W1973029228 cites W2045263347 @default.
- W1973029228 cites W2046463507 @default.
- W1973029228 cites W2057312794 @default.
- W1973029228 cites W2060492750 @default.
- W1973029228 cites W2065176754 @default.
- W1973029228 cites W2068312858 @default.
- W1973029228 cites W2070870036 @default.
- W1973029228 cites W2076004384 @default.
- W1973029228 cites W2076278107 @default.
- W1973029228 cites W2076622858 @default.
- W1973029228 cites W2077268941 @default.
- W1973029228 cites W2080693374 @default.
- W1973029228 cites W2081528204 @default.
- W1973029228 cites W2082305534 @default.
- W1973029228 cites W2083088477 @default.
- W1973029228 cites W2088870617 @default.
- W1973029228 cites W2091237955 @default.
- W1973029228 cites W2093701962 @default.
- W1973029228 cites W2094129731 @default.
- W1973029228 cites W2094414291 @default.
- W1973029228 cites W2094820352 @default.
- W1973029228 cites W2104166397 @default.
- W1973029228 cites W2111858259 @default.
- W1973029228 cites W2118997899 @default.
- W1973029228 cites W2147562143 @default.
- W1973029228 cites W2167009502 @default.
- W1973029228 cites W2174711518 @default.
- W1973029228 cites W2179123396 @default.
- W1973029228 cites W4250823606 @default.
- W1973029228 cites W2059266904 @default.
- W1973029228 doi "https://doi.org/10.1063/1.477815" @default.
- W1973029228 hasPublicationYear "1999" @default.
- W1973029228 type Work @default.
- W1973029228 sameAs 1973029228 @default.
- W1973029228 citedByCount "12" @default.
- W1973029228 countsByYear W19730292282012 @default.
- W1973029228 countsByYear W19730292282015 @default.
- W1973029228 crossrefType "journal-article" @default.
- W1973029228 hasAuthorship W1973029228A5055636861 @default.
- W1973029228 hasConcept C121332964 @default.
- W1973029228 hasConcept C123669783 @default.
- W1973029228 hasConcept C132439834 @default.
- W1973029228 hasConcept C145148216 @default.
- W1973029228 hasConcept C147597530 @default.
- W1973029228 hasConcept C147789679 @default.
- W1973029228 hasConcept C148898269 @default.
- W1973029228 hasConcept C152365726 @default.
- W1973029228 hasConcept C15744967 @default.
- W1973029228 hasConcept C159467904 @default.
- W1973029228 hasConcept C17525397 @default.
- W1973029228 hasConcept C178790620 @default.
- W1973029228 hasConcept C185592680 @default.
- W1973029228 hasConcept C26873012 @default.
- W1973029228 hasConcept C2776029896 @default.
- W1973029228 hasConcept C2779892579 @default.
- W1973029228 hasConcept C2780471494 @default.
- W1973029228 hasConcept C32909587 @default.
- W1973029228 hasConcept C62520636 @default.
- W1973029228 hasConcept C68801617 @default.
- W1973029228 hasConcept C77805123 @default.
- W1973029228 hasConcept C89169741 @default.