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- W1973032072 abstract "Thermal NO dissociation reactions in the solid phase of mononitrosylcobalt(III) complexes with the formula, CoL4NO (L4 denotes tetradentate ligands such as bzacen, salen and its 5-NO2, 5-Cl, and 5-Me derivatives2) have been investigated by means of TG, DSC, and pyrolysis gas chromatographic analyses. The complexes eliminated one mole of NO per mole in the 160–300°C range and reproduced CoL4 complexes which possessed X-ray diffraction patterns similar to those of authentic CoL4 complexes. The kinetic analyses indicated that the NO dissociation process followed a first-order equation; the activation enthalpy values were 120–124 kJ mol−1, being invariable irrespective of the nature of L4. The values of heat of NO dissociation, determined by the DSC method were in the range 40–50 kJ mol−1. From these thermochemical data and the data of heat of solution of NO, the NO dissociation energies in solution were calculated to be 52–61 kJ mol−1. The thermal data were discussed in terms of the nature of the CoNO bond." @default.
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- W1973032072 date "1985-03-01" @default.
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- W1973032072 title "Thermal characterization of nitrogen monoxide dissociation reactions of nitrosyl complexes in the solid phase. Mononitrosylcobalt(III) complexes with mixed ligand tetradentate Schiff bases" @default.
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- W1973032072 doi "https://doi.org/10.1016/0040-6031(85)85400-9" @default.
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