FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W1973039679> ?p ?o ?g. }

• W1973039679 endingPage "4385" @default.
• W1973039679 startingPage "4374" @default.
• W1973039679 abstract "Dibenzyldimethylammonium (DBDM) cations, singly fluorinated at the ortho, meta, and para positions of the aromatic ring, have been investigated as structure-directing agents (SDAs) for the synthesis of all-silica zeolites in fluoride media and compared with the nonfluorinated molecule. The nonfluorinated DBDM cation can direct the synthesis either to an all-silica zeolite beta or to an all-silica zeolite ZSM-50 with the EUO framework topology. Under the same conditions that DBDM gives zeolite beta, benzyl-orthofluorobenzyldimethylammonium (o-FDBDM) readily directs the crystallization of pure all-silica ZSM-50 [Cmma, a = 13.726(3) Å, b = 22.171(5) Å, c = 20.254(4) Å]. Replacing o-FDBDM by the para fluoro derivative (p-FDBDM) results in a much slower crystallization of ZSM-50 whereas no crystalline product results if the meta fluoro derivative (m-FDBDM) is added. Single-crystal diffraction studies of selected ZSM-50 crystals prepared using DBDM and o-FDBDM determine the location of the template and of charge-balancing fluoride atoms bound to framework silicon atoms and included within [415462] cages in the framework. Furthermore, the o-FDBDM is found to order within the structure, with the fluorine-containing aromatic rings occupying channel, rather than cavity, locations. Computer simulations indicate how the position of fluorine in the SDA influences the template ordering." @default.
• W1973039679 created "2016-06-24" @default.
• W1973039679 creator A5046405931 @default.
• W1973039679 creator A5049970193 @default.
• W1973039679 creator A5055146293 @default.
• W1973039679 creator A5055432131 @default.
• W1973039679 creator A5056584645 @default.
• W1973039679 creator A5070046535 @default.
• W1973039679 creator A5075080825 @default.
• W1973039679 date "2005-07-26" @default.
• W1973039679 modified "2023-10-18" @default.
• W1973039679 title "Cooperative Structure-Directing Effect of Fluorine-Containing Organic Molecules and Fluoride Anions in the Synthesis of Zeolites" @default.
• W1973039679 cites W111015088 @default.
• W1973039679 cites W1531578847 @default.
• W1973039679 cites W1574026801 @default.
• W1973039679 cites W1973303143 @default.
• W1973039679 cites W1980770687 @default.
• W1973039679 cites W1985136736 @default.
• W1973039679 cites W1986909878 @default.
• W1973039679 cites W1987921583 @default.
• W1973039679 cites W1989838495 @default.
• W1973039679 cites W2013376295 @default.
• W1973039679 cites W2023820214 @default.
• W1973039679 cites W2023832328 @default.
• W1973039679 cites W2037097399 @default.
• W1973039679 cites W2064339463 @default.
• W1973039679 cites W2069018922 @default.
• W1973039679 cites W2070302490 @default.
• W1973039679 cites W2073885652 @default.
• W1973039679 cites W2085765304 @default.
• W1973039679 cites W2091802431 @default.
• W1973039679 cites W2093966310 @default.
• W1973039679 cites W2100816704 @default.
• W1973039679 cites W2151159767 @default.
• W1973039679 cites W2170006871 @default.
• W1973039679 doi "https://doi.org/10.1021/cm050971j" @default.
• W1973039679 hasPublicationYear "2005" @default.
• W1973039679 type Work @default.
• W1973039679 sameAs 1973039679 @default.
• W1973039679 citedByCount "38" @default.
• W1973039679 countsByYear W19730396792012 @default.
• W1973039679 countsByYear W19730396792013 @default.
• W1973039679 countsByYear W19730396792015 @default.
• W1973039679 countsByYear W19730396792016 @default.
• W1973039679 countsByYear W19730396792017 @default.
• W1973039679 countsByYear W19730396792018 @default.
• W1973039679 countsByYear W19730396792021 @default.
• W1973039679 countsByYear W19730396792022 @default.
• W1973039679 countsByYear W19730396792023 @default.
• W1973039679 crossrefType "journal-article" @default.
• W1973039679 hasAuthorship W1973039679A5046405931 @default.
• W1973039679 hasAuthorship W1973039679A5049970193 @default.
• W1973039679 hasAuthorship W1973039679A5055146293 @default.
• W1973039679 hasAuthorship W1973039679A5055432131 @default.
• W1973039679 hasAuthorship W1973039679A5056584645 @default.
• W1973039679 hasAuthorship W1973039679A5070046535 @default.
• W1973039679 hasAuthorship W1973039679A5075080825 @default.
• W1973039679 hasConcept C106159729 @default.
• W1973039679 hasConcept C111771559 @default.
• W1973039679 hasConcept C114614502 @default.
• W1973039679 hasConcept C115624301 @default.
• W1973039679 hasConcept C161790260 @default.
• W1973039679 hasConcept C162324750 @default.
• W1973039679 hasConcept C178790620 @default.
• W1973039679 hasConcept C179104552 @default.
• W1973039679 hasConcept C184720557 @default.
• W1973039679 hasConcept C185592680 @default.
• W1973039679 hasConcept C203036418 @default.
• W1973039679 hasConcept C2778077586 @default.
• W1973039679 hasConcept C2780378348 @default.
• W1973039679 hasConcept C2780828025 @default.
• W1973039679 hasConcept C32909587 @default.
• W1973039679 hasConcept C33923547 @default.
• W1973039679 hasConcept C506198293 @default.
• W1973039679 hasConcept C8010536 @default.
• W1973039679 hasConceptScore W1973039679C106159729 @default.
• W1973039679 hasConceptScore W1973039679C111771559 @default.
• W1973039679 hasConceptScore W1973039679C114614502 @default.
• W1973039679 hasConceptScore W1973039679C115624301 @default.
• W1973039679 hasConceptScore W1973039679C161790260 @default.
• W1973039679 hasConceptScore W1973039679C162324750 @default.
• W1973039679 hasConceptScore W1973039679C178790620 @default.
• W1973039679 hasConceptScore W1973039679C179104552 @default.
• W1973039679 hasConceptScore W1973039679C184720557 @default.
• W1973039679 hasConceptScore W1973039679C185592680 @default.
• W1973039679 hasConceptScore W1973039679C203036418 @default.
• W1973039679 hasConceptScore W1973039679C2778077586 @default.
• W1973039679 hasConceptScore W1973039679C2780378348 @default.
• W1973039679 hasConceptScore W1973039679C2780828025 @default.
• W1973039679 hasConceptScore W1973039679C32909587 @default.
• W1973039679 hasConceptScore W1973039679C33923547 @default.
• W1973039679 hasConceptScore W1973039679C506198293 @default.
• W1973039679 hasConceptScore W1973039679C8010536 @default.
• W1973039679 hasIssue "17" @default.
• W1973039679 hasLocation W19730396791 @default.
• W1973039679 hasOpenAccess W1973039679 @default.
• W1973039679 hasPrimaryLocation W19730396791 @default.
• W1973039679 hasRelatedWork W1967693895 @default.

• next