Matches in SemOpenAlex for { <https://semopenalex.org/work/W1973065522> ?p ?o ?g. }
Showing items 1 to 100 of
100
with 100 items per page.
- W1973065522 endingPage "175" @default.
- W1973065522 startingPage "165" @default.
- W1973065522 abstract "The criteria for an adsorbed layer to undergo a reversible phase transition on an electrode surface are examined by means of classical thermodynamics. It is shown that, although this process takes place always at a constant value of the potential drop across the adsorbed layer, it may occur at either a constant value of the applied potential or over a certain range of applied potentials. The first possibility can be realised when the concentration of ions in the diffuse layer is high enough to produce an approximately equipotential plane just beyond the adsorbed layer or when the diffuse layer is imposed to undergo a kind of phase transition characterised by its separation into two parts with different total electrical charge but the same potential drop or the transition extends throughout the interface. If neither of the above processes can be realised, then the second possibility is very likely due to a diffuse layer effect. For the examination of the diffuse layer effect in more detail, the classical supersaturation theory is extended to two-dimensional phase transitions on electrode surfaces and an attempt is made to explain the existence and extent of metastable states as well as the mechanism and the properties of irreversible transitions. The results obtained are compared with current views on two-dimensional phase transitions." @default.
- W1973065522 created "2016-06-24" @default.
- W1973065522 creator A5057758956 @default.
- W1973065522 date "1998-04-01" @default.
- W1973065522 modified "2023-10-18" @default.
- W1973065522 title "Diffuse layer effect and effect of curvature on the mechanism and the properties of phase transitions at electrified interfaces" @default.
- W1973065522 cites W1531317046 @default.
- W1973065522 cites W1535528631 @default.
- W1973065522 cites W1582582218 @default.
- W1973065522 cites W1583370727 @default.
- W1973065522 cites W1591664180 @default.
- W1973065522 cites W1965235777 @default.
- W1973065522 cites W1971627182 @default.
- W1973065522 cites W1980461113 @default.
- W1973065522 cites W1985176056 @default.
- W1973065522 cites W2009487076 @default.
- W1973065522 cites W2032002847 @default.
- W1973065522 cites W2032361614 @default.
- W1973065522 cites W2033571877 @default.
- W1973065522 cites W2042438728 @default.
- W1973065522 cites W2050349213 @default.
- W1973065522 cites W2070140352 @default.
- W1973065522 cites W2090948045 @default.
- W1973065522 cites W2095411993 @default.
- W1973065522 cites W40280440 @default.
- W1973065522 cites W4251724664 @default.
- W1973065522 doi "https://doi.org/10.1016/s0022-0728(97)00580-9" @default.
- W1973065522 hasPublicationYear "1998" @default.
- W1973065522 type Work @default.
- W1973065522 sameAs 1973065522 @default.
- W1973065522 citedByCount "9" @default.
- W1973065522 crossrefType "journal-article" @default.
- W1973065522 hasAuthorship W1973065522A5057758956 @default.
- W1973065522 hasConcept C121332964 @default.
- W1973065522 hasConcept C147789679 @default.
- W1973065522 hasConcept C149288129 @default.
- W1973065522 hasConcept C150394285 @default.
- W1973065522 hasConcept C159467904 @default.
- W1973065522 hasConcept C17525397 @default.
- W1973065522 hasConcept C178790620 @default.
- W1973065522 hasConcept C185592680 @default.
- W1973065522 hasConcept C18787249 @default.
- W1973065522 hasConcept C195065555 @default.
- W1973065522 hasConcept C2524010 @default.
- W1973065522 hasConcept C26873012 @default.
- W1973065522 hasConcept C2779227376 @default.
- W1973065522 hasConcept C2781345722 @default.
- W1973065522 hasConcept C33923547 @default.
- W1973065522 hasConcept C41008148 @default.
- W1973065522 hasConcept C44280652 @default.
- W1973065522 hasConcept C62520636 @default.
- W1973065522 hasConcept C68801617 @default.
- W1973065522 hasConcept C76155785 @default.
- W1973065522 hasConcept C84130051 @default.
- W1973065522 hasConcept C89464430 @default.
- W1973065522 hasConcept C97355855 @default.
- W1973065522 hasConceptScore W1973065522C121332964 @default.
- W1973065522 hasConceptScore W1973065522C147789679 @default.
- W1973065522 hasConceptScore W1973065522C149288129 @default.
- W1973065522 hasConceptScore W1973065522C150394285 @default.
- W1973065522 hasConceptScore W1973065522C159467904 @default.
- W1973065522 hasConceptScore W1973065522C17525397 @default.
- W1973065522 hasConceptScore W1973065522C178790620 @default.
- W1973065522 hasConceptScore W1973065522C185592680 @default.
- W1973065522 hasConceptScore W1973065522C18787249 @default.
- W1973065522 hasConceptScore W1973065522C195065555 @default.
- W1973065522 hasConceptScore W1973065522C2524010 @default.
- W1973065522 hasConceptScore W1973065522C26873012 @default.
- W1973065522 hasConceptScore W1973065522C2779227376 @default.
- W1973065522 hasConceptScore W1973065522C2781345722 @default.
- W1973065522 hasConceptScore W1973065522C33923547 @default.
- W1973065522 hasConceptScore W1973065522C41008148 @default.
- W1973065522 hasConceptScore W1973065522C44280652 @default.
- W1973065522 hasConceptScore W1973065522C62520636 @default.
- W1973065522 hasConceptScore W1973065522C68801617 @default.
- W1973065522 hasConceptScore W1973065522C76155785 @default.
- W1973065522 hasConceptScore W1973065522C84130051 @default.
- W1973065522 hasConceptScore W1973065522C89464430 @default.
- W1973065522 hasConceptScore W1973065522C97355855 @default.
- W1973065522 hasIssue "1-2" @default.
- W1973065522 hasLocation W19730655221 @default.
- W1973065522 hasOpenAccess W1973065522 @default.
- W1973065522 hasPrimaryLocation W19730655221 @default.
- W1973065522 hasRelatedWork W1969927671 @default.
- W1973065522 hasRelatedWork W2017887805 @default.
- W1973065522 hasRelatedWork W2030069285 @default.
- W1973065522 hasRelatedWork W2088288202 @default.
- W1973065522 hasRelatedWork W212761123 @default.
- W1973065522 hasRelatedWork W2319483687 @default.
- W1973065522 hasRelatedWork W2364133764 @default.
- W1973065522 hasRelatedWork W2409565610 @default.
- W1973065522 hasRelatedWork W2950277148 @default.
- W1973065522 hasRelatedWork W4211250440 @default.
- W1973065522 hasVolume "446" @default.
- W1973065522 isParatext "false" @default.
- W1973065522 isRetracted "false" @default.
- W1973065522 magId "1973065522" @default.
- W1973065522 workType "article" @default.