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- W1973073732 abstract "A chemically modified electrode constructed by mixing nickel tetrasulfonated phthalocyanine (NiTsPc) immobilized on modified silica gel with carbon paste showed a redox process with a midpoint potential of 0.44 V vs sce. Experiments carried out with different supporting electrolytes suggested an effect due to the nature of the anion. The solution pH does not affect the midpoint potential but the peak current increases when the pH is decreased. The immobilization procedure causes an increase in the monomeric form of the complex. The electrochemical property of NiTsPc adsorbed onto modified silica showed good stability even in acidic media (pH=2) and the ability to catalyze the electro-oxidation of cysteine at 0.5 V vs sce." @default.
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- W1973073732 date "1998-05-01" @default.
- W1973073732 modified "2023-10-03" @default.
- W1973073732 title "Anodic oxidation of cysteine catalysed by nickel tetrasulphonated phthalocyanine immobilized on silica gel modified with titanium (IV) oxide" @default.
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- W1973073732 doi "https://doi.org/10.1016/s0013-4686(97)00323-x" @default.
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