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• W1973083029 startingPage "1354" @default.
• W1973083029 abstract "Abstract A clickable alkyne monomer, PgMA, was successfully polymerized in a well‐controlled manner via single electron transfer initiation and propagation through the radical addition fragmentation chain transfer (SET‐RAFT) method. The living nature of the polymerization was confirmed by the first‐order kinetic plots, the linear relationships between molecular weights and the monomer conversions while keeping relatively narrow $overline M _{rm w} /overline M _{rm n}$ (≤1.55), and the successful chain‐extension with MMA. The better controllability of SET‐RAFT than other CRP methods is attributed to the less competitive termination in view of the presence of the CTA as well as the Cu(II) that is generated in situ. Moreover, a one‐pot/one‐step technique combining SET‐RAFT and “click chemistry” methods has been successfully employed to prepare the side‐chain functionalized polymers. magnified image" @default.
• W1973083029 created "2016-06-24" @default.
• W1973083029 creator A5013617244 @default.
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• W1973083029 creator A5068428294 @default.
• W1973083029 date "2010-07-26" @default.
• W1973083029 modified "2023-10-16" @default.
• W1973083029 title "SET-RAFT Polymerization of Progargyl Methacrylate and a One-Pot/One-Step Preparation of Side-chain Functionalized Polymers <i>via</i> Combination of SET-RAFT and Click Chemistry" @default.
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• W1973083029 doi "https://doi.org/10.1002/marc.201000008" @default.
• W1973083029 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/21567535" @default.
• W1973083029 hasPublicationYear "2010" @default.
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