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- W1973092011 abstract "Photocatalytic activity of microporous titanosilicate ETS-10 has been studied in water. The photoactivated ETS-10 shows catalytic activity driven by size and polarity of substrates. ETS-10 efficiently catalyzes a conversion of substrates with a size larger than the pore diameter of ETS-10. In contrast, the reactivity of small substrates depends strongly on substrate polarity; less polar substrates show higher reactivity on ETS-10. Electron spin resonance analysis reveals that large substrates or less polar substrates scarcely diffuse inside the highly polarized micropores of ETS-10 and, hence, react efficiently with hydroxyl radicals (*OH) formed on titanol (Ti-OH) groups exposed on the external surface of ETS-10. In contrast, small polar substrates diffuse easily inside the micropores of ETS-10 and scarcely react with *OH, resulting in low reactivity. The photocatalytic activity of ETS-10 is successfully applicable to selective transformations of large reactants or less polar reactants to small polar products, enabling highly selective dehalogenation and hydroxylation of aromatics." @default.
- W1973092011 created "2016-06-24" @default.
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- W1973092011 date "2008-10-10" @default.
- W1973092011 modified "2023-10-16" @default.
- W1973092011 title "Selective Photocatalytic Transformations on Microporous Titanosilicate ETS-10 Driven by Size and Polarity of Molecules" @default.
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- W1973092011 doi "https://doi.org/10.1021/la802513g" @default.
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